Styrene → 1-Octene

HRID 892676

Reaction equation

FC(F)(F)S(Cl)(=O)=O.F[C:10](F)(S(Cl)(=O)=O)[C:11](F)(F)[C:12](F)(F)[C:13](F)(F)[C:14](F)(F)[C:15](F)(F)F.[CH2:32]=[CH:33][C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1>>[CH2:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH3:15].[CH2:32]=[CH:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38].[CH2:32]=[CH:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]

Participants

Reactant 3

HCID 7501Styrene

HCID 79000Trifluoromethanesulfonyl chloride

HCID 1003741,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluorohexane-1-sulphonyl chloride

Product 3

HCID 81251-Octene

HCID 115971-Hexene

HCID 116101-Heptene

Procedure

Reactions were carried out generally in accordance with Example 1, except that trifluoromethanesulfonyl chloride was replaced by perfluorohexanesulfonyl chloride and styrene was replaced, respcetively, by 1-hexene (Example 15), 1-heptene (Example 16) and 1-octene (Example 17), whereby 1-butyl-1-chloro-2-perfluorohexylethane (Example 15), 1-heptyl-1-chloro-2-perfluorohexylethane (Example 16) and 1-hexyl-1-chloro-2-perfluorohexylethane (Example 17) were obtained, respectively, at a yield of 63%, 69% and 73%. The results of analyses of respective products are set forth below.

Sources & evidence

ORD record: ord-1f97f4870f714f069b7a4546ba978e7f
Source dataset: uspto-grants-1992_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05118879

Linked notes

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