Tetrahydrofuran → Ethyl 6-[2-(3-hydroxy-5-phenylpent-1-enyl)-4-oxopyran-3-yl]oxyhexanoate

HRID 932373

Reaction equation

HRID 932373 reaction equation
[CH2:31]([BH-:32]([CH2:33][CH3:34])[CH2:35][CH3:36])[CH3:37].[Li+:38].[O:1]=[C:2]([CH:3]=[CH:4][c:5]1[o:6][cH:7][cH:8][c:9](=[O:22])[c:10]1[O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17](=[O:18])[O:19][CH2:20][CH3:21])[CH2:23][CH2:24][c:25]1[cH:26][cH:27][cH:28][cH:29][cH:30]1.[O:39]1[CH2:40][CH2:41][CH2:42][CH2:43]1>>[OH:1][CH:2]([CH:3]=[CH:4][c:5]1[o:6][cH:7][cH:8][c:9](=[O:22])[c:10]1[O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17](=[O:18])[O:19][CH2:20][CH3:21])[CH2:23][CH2:24][c:25]1[cH:26][cH:27][cH:28][cH:29][cH:30]1

Participants

5

Reactant 4

HCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 2723994TriethylboranuideHCID 54068129Ethyl 6-[4-oxo-2-(3-oxo-5-phenylpent-1-enyl)pyran-3-yl]oxyhexanoate

Product 1

HCID 54177131Ethyl 6-[2-(3-hydroxy-5-phenylpent-1-enyl)-4-oxopyran-3-yl]oxyhexanoate

Sources & evidence

ORD record
ord-bd82bd9592b6470b8aff3fa33b7f4b47
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Linked notes

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