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Dimethyl Sulfoxide → 5-(Tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-pentanal

HRID 951811
Notes
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Reaction equation

HRID 951811 reaction equation
[C:11]([CH3:12])([CH3:13])([CH3:14])[Si:15]([O:16][CH2:17][CH2:18][C:19]([CH2:20][CH2:21][OH:22])([CH3:23])[CH3:24])([CH3:25])[CH3:26].[CH3:27][CH2:28][N:29]([CH2:30][CH3:31])[CH2:32][CH3:33].[CH3:7][S:8](=[O:9])[CH3:10].[Cl:1][C:2]([C:3]([Cl:4])=[O:5])=[O:6].[Cl:34][CH2:35][Cl:36].[OH2:37]>>[C:11]([CH3:12])([CH3:13])([CH3:14])[Si:15]([O:16][CH2:17][CH2:18][C:19]([CH2:20][CH:21]=[O:22])([CH3:23])[CH3:24])([CH3:25])[CH3:26]
ParticipantsSources & evidenceReaction notes

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 962WaterHCID 6344DichloromethaneHCID 8471TriethylamineHCID 65578Oxalyl chlorideHCID 107529805-(Tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-pentan-1-ol

Product 1

HCID 219327085-(Tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-pentanal

Sources & evidence

ORD record
ord-35afff2fa9334b8da627a974ab48b1ef
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D
DOI
10.1039/C8SC04228D

Reaction notes

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On this pageParticipantsSources & evidenceReaction notes