Sodium Ion → Cyclopentanol, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-

Reaction equation

[C:10]([CH3:11])([CH3:12])([CH3:13])[Si:14]([CH3:15])([CH3:16])[Cl:17].[CH2:18]1[O:19][CH2:20][CH2:21][CH2:22]1.[CH2:23]([O:24][C:25](=[O:26])[CH3:27])[CH3:28].[CH:3]1([OH:9])[CH2:4][CH:5]([OH:8])[CH2:6][CH2:7]1.[H-:1].[Na+:2]>>[CH:3]1([OH:9])[CH2:4][CH:5]([O:8][Si:14]([C:10]([CH3:11])([CH3:12])[CH3:13])([CH3:15])[CH3:16])[CH2:6][CH2:7]1

Participants

Reactant 6

HCID 923Sodium Ion

HCID 8028Tetrahydrofuran

HCID 8857Ethyl Acetate

HCID 28928tert-Butyldimethylsilyl chloride

HCID 100165Cyclopentane-1,3-diol

HCID 166653Hydride

Product 1

HCID 21938628Cyclopentanol, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-

Sources & evidence

ORD record: ord-01790d930d3349989d5b8e804a447983
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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