Carbon Dioxide → [Chloro(dimethylamino)methylidene]-dimethylazanium chloride

HRID 964192

Reaction equation

HRID 964192 reaction equation
C(Cl)(=O)C([Cl:4])=O.[CH3:7][N:8]([CH3:14])[C:9](=O)[N:10]([CH3:12])[CH3:11].C(=O)=O.[C]=O>C(Cl)(Cl)(Cl)Cl>[Cl-:4].[CH3:7][N:8]([CH3:14])[C:9]([Cl:4])=[N+:10]([CH3:12])[CH3:11]

Participants

6

Reactant 4

HCID 280Carbon DioxideHCID 12437TetramethylureaHCID 65578Oxalyl chlorideHCID 178418416HCID 178418416, compound

Product 1

HCID 177416803[Chloro(dimethylamino)methylidene]-dimethylazanium chloride

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent2×

Procedure

A solution of 2.5 ml (0.027 mol) of oxalyl chloride in 15 ml of anhydrous carbon tetrachloride is poured dropwise into a solution of 3.4 ml (0.027 mol) of tetramethylurea in 10 ml of anhydrous carbon tetrachloride kept stirring under a nitrogen atmosphere. While the stirring is continued, the reaction medium is maintained at reflux until the evolution of carbon dioxide and carbon monoxide gases has ceased. The formamidinium chloride obtained in the form of a white solid is dissolved at 0° C. in 30 ml of anhydrous acetonitrile.

Workup

  1. temperaturethe reaction medium is maintained

Sources & evidence

ORD record
ord-263341a7e2eb410480d96fc7b36949ab
Source dataset
uspto-grants-1998_06
Patent number
US05767229

Linked notes

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