1-Propanol → HCID 13117144, compound
Reaction equation
[CH2:1]([CH:6]1[C:10](O)([CH3:11])[CH:9]=[CH:8][C:7]1=[O:13])[CH2:2][CH2:3][CH2:4][CH3:5].C1(C)C=CC(S(O)(=O)=O)=CC=1.[CH2:25]([OH:28])[CH2:26][CH3:27]>>[CH2:1]([C:6]1[C:7](=[O:13])[CH2:8][CH:9]([O:28][CH2:25][CH2:26][CH3:27])[C:10]=1[CH3:11])[CH2:2][CH2:3][CH2:4][CH3:5]Participants
4
Procedure
Into the same flask as used in Example 1, 2-n-pentyl-3-hydroxy-3-methyl-4-cyclopentenone (0.1 mol; 1 part), n-propanol (5 parts) and p-toluenesulfonic acid (1/20 part) were charged, and the mixture was stirred at a temperature of 40° to 70° C. for 5 hours. After completion of the reaction, the mixture was treated in the same manner as in Example 25 to obtain 2-n-pentyl-3-methyl-4-n-propoxy-2-cyclopentenone. Yield, 96%. nD19 1.4792.
Workup
- additionwere charged
- custom