Triphenylphosphine → N-(4-p-Tolylethynyl-phenyl)-methanesulfonamide

HRID 97905

Reaction equation

HRID 97905 reaction equation
[C:13](#[CH:14])[c:15]1[cH:16][cH:17][c:18]([CH3:21])[cH:19][cH:20]1.[Cu:63][I:64].[I:1][c:2]1[cH:3][cH:4][c:5]([NH:8][S:9](=[O:10])(=[O:11])[CH3:12])[cH:6][cH:7]1.[Pd:22]([Cl:23])[Cl:24].[c:25]1([P:26]([c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[c:33]2[cH:34][cH:35][cH:36][cH:37][cH:38]2)[cH:39][cH:40][cH:41][cH:42][cH:43]1.[c:44]1([P:45]([c:46]2[cH:47][cH:48][cH:49][cH:50][cH:51]2)[c:52]2[cH:53][cH:54][cH:55][cH:56][cH:57]2)[cH:58][cH:59][cH:60][cH:61][cH:62]1>>[c:2]1([C:14]#[C:13][c:15]2[cH:16][cH:17][c:18]([CH3:21])[cH:19][cH:20]2)[cH:3][cH:4][c:5]([NH:8][S:9](=[O:10])(=[O:11])[CH3:12])[cH:6][cH:7]1

Participants

6

Reactant 5

HCID 11776Triphenylphosphine2×HCID 13018p-EthynyltolueneHCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 836147N-(4-iodophenyl)methanesulfonamide

Product 1

HCID 68511472N-(4-p-Tolylethynyl-phenyl)-methanesulfonamide

Sources & evidence

ORD record
ord-7089bd944974491c8235fb13be2cd239
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Linked notes

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