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Hydrogen Peroxide → Hydrogen Peroxide

HRID 982178
Notes
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Reaction equation

HRID 982178 reaction equation
[C:1]([OH:5])(=[O:4])[CH2:2][CH3:3].[OH:6][OH:7]>B(O)(O)O.C(Cl)CCl>[CH3:3][CH2:2][C:1]([O:5][OH:6])=[O:4].[C:1]([OH:5])(=[O:4])[CH2:2][CH3:3].[OH:6][OH:7]
ParticipantsProcedureSources & evidenceReaction notes

Participants

7

Reactant 2

HCID 784Hydrogen PeroxideHCID 1032Propionic Acid

Product 3

HCID 784Hydrogen PeroxideHCID 1032Propionic AcidHCID 65136Perpropionic acid

Reagents, catalysts & solvents 2

HCID 7628Boric AcidCatalystHCID 111,2-DichloroethaneSolvent

Procedure

reacting propionic acid with hydrogen peroxide in the presence of a boric acid catalyst and an azeotropic solvent comprising dichloro-1, 2-ethane in a first reaction vessel to form a crude perpropionic acid, unreacted propionic acid, hydrogen peroxide, catalyst and solvent, while continuously eliminating the water of reaction by azeotropic entrainment with said solvent;

Sources & evidence

ORD record
ord-ad094a892ecb404da724eafe549d3b6e
Source dataset
uspto-grants-1991_02
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04994583

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes