Acetic Acid → 1-Nitroadamantane

HRID 992145

Reaction equation

HRID 992145 reaction equation
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[OH:11][N:12]1C(=O)C2=CC=CC=C2C1=O.C(O)(=[O:25])C>>[N+:12]([C:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2)([O-:11])=[O:25]

Participants

4

Reactant 3

HCID 176Acetic AcidHCID 9238AdamantaneHCID 10665N-Hydroxyphthalimide

Product 1

HCID 641651-NitroadamantaneYield 81%

Procedure

1.8 g (0.024 mole based on N2O3 basis) of the frozen blue liquid, 1 mmole of adamantane, 0.05 mmole of N-hydroxyphthalimide and 5 ml of acetic acid were mixed, and then the mixture was reacted for 10 hours at 100° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, nitroadamantane (yield 81%) was formed with conversion of 99%.

Workup

  1. customthe mixture was reacted for 10 hours at 100° C.

Sources & evidence

ORD record
ord-02f480573d1a4329bcc8d5451fa6a9a5
Source dataset
uspto-grants-2002_10
Patent number
US06468487B1

Linked notes

Loading…