(R)-(-)-4,12-ビス(ジフェニルホスフィノ)-[2.2]-パラシクロファン

(R)-Phanephos

HCID 10864772

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 364732-88-7
標準SMILES: c1ccc(P(c2ccccc2)c2cc3ccc2CCc2ccc(c(P(c4ccccc4)c4ccccc4)c2)CC3)cc1
InChIKey: GYZZZILPVUYAFJ-UHFFFAOYSA-N
分子式: C40H34P2
平均分子量: 576.6 g/mol
単同位体質量: 576.21357508

名称と識別子

優先名称: (R)-Phanephos
IUPAC: (11-diphenylphosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl)-diphenylphosphane
現地名: (R)-(-)-4,12-ビス(ジフェニルホスフィノ)-[2.2]-パラシクロファン
英語名: (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
分子式: C40H34P2
分子量: 576.65

名称と別名

(R)-Phanephos364732-88-7DTXSID301045593RefChem:407439DTXCID901527519192463-40-4(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane(S)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophaneMFCD03094575(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane(Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane

名称をさらに表示

(R)-(-)-4,12-ビス(ジフェニルホスフィノ)-[2.2]-パラシクロファン(R)-Phanephos, 98%, ee 98%(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%eePhosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE(11-diphenylphosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl)-diphenylphosphanePhanePhos(S)-Phanephosstereoisomer of 1,1'-Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-diphenylphosphine][2.2]Phanephos12,43-bis(diphenylphosphaneyl)-1,4(1,4)-dibenzenacyclohexaphanePhanePHO S

データベース識別子

CAS: 364732-88-7
PubChem CID: 10864772
DTXSID: DTXSID301045593
EC Number: 690-034-8
Nikkaji: J1.895.601B、J2.182.859I、J941.569F

物性

構造計算による物性

XLogP: 9.8
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 6
重原子数: 42
形式電荷: 0
複雑度: 683

物理化学的性質

融点: 222 · 222-225°C
比旋光度: -62.6 ° · -62.6° (c 3.11, CH2Cl2)
貯蔵温度: Inert atmosphere,Room Temperature
外見: 個体
色: 白い
InChIKey: GYZZZILPVUYAFJ-UHFFFAOYSA-N
SMILES: P(c7ccccc7)(c6ccccc6)c1c2ccc(c1)CCc3c(cc(cc3)CC2)P(c5ccccc5)c4ccccc4
CAS データベース: 364732 · 364732-88-7

安全と法規制

GHS分類

GHS Classification · 5 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.