2-Benzoylbenzoic Acid → Bismuth(III)benzoyl benzoate

HRID 1881391

反応式

HRID 1881391 の反応式
C1([Bi:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)C2C=CC=CC=2)C=CC=CC=1.C([C:28]1[CH:36]=[CH:35][CH:34]=[CH:33][C:29]=1[C:30]([OH:32])=[O:31])(=O)C1C=CC=CC=1.[O:37]1CCOC[CH2:38]1>>[C:30]([O:32][C:38](=[O:37])[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)(=[O:31])[C:29]1[CH:28]=[CH:36][CH:35]=[CH:34][CH:33]=1.[Bi+3:7]

参加物

4

反応物 3

HCID 68132-Benzoylbenzoic AcidHCID 11774TriphenylbismuthHCID 312751,4-Dioxane2 回

生成物 1

HCID 86645404Bismuth(III)benzoyl benzoate

反応条件

温度
110 °C

実験手順

In a dry three-neck-flask, 1.5 g (3.4 mmol) triphenylbismuth dissolved in 5 ml dioxane is added to a solution of 2.31 g (10.2 mmol) benzoylbenzoic acid in 3 ml dioxane under argon and the resulting solution is heated to 110° C. for 1.5 hours. The mixture is cooled to room temperature and concentrated yielding 1.5 g of the product. The structure is confirmed by 1H-NMR and 13C-NMR spectra.

後処理

  1. temperatureThe mixture is cooled to room temperature
  2. concentrationconcentrated

出典と根拠

ORDレコード
ord-efebecdbd6694996a96e921215422c81
出典データセット
uspto-grants-2012_11
特許番号
US08318830B2

関連ノート

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