二酢酸コバルト(II)·4水和物
Cobalt(II) acetate tetrahydrate
基本情報
- CAS
6147-53-1- 標準SMILES
CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Co+2]- InChIKey
ZBYYWKJVSFHYJL-UHFFFAOYSA-L- 分子式
- C4H6CoO4.4H2O
- 平均分子量
- 249.08 g/mol
- 単同位体質量
- 249.00206241
名称と識別子
- 優先名称
- Cobalt(II) acetate tetrahydrate
- IUPAC
- cobalt(2+);diacetate;tetrahydrate
- 現地名
- 二酢酸コバルト(II)·4水和物
- 英語名
- Cobalt(II) acetate tetrahydrate
- 分子式
- C4H14CoO8
- 分子量
- 249.08
名称と別名
Cobalt(II) acetate tetrahydrate6147-53-1Cobaltous acetate tetrahydrateCCRIS 9441UNII-7648Z91O1NAcetic acid, cobalt(2+) salt, tetrahydrate7648Z91O1NDTXSID80210423BIS(ACETATO)TETRAAQUOCOBALTCOBALTOUS ACETATE TETRAHYDRATE [MI]Cobalt (II) diacetateRefChem:127234
名称をさらに表示
二酢酸コバルト(II)·4水和物二酢酸コバルト(II)·四水和物酢酸コバルト四水和物酢酸コバルト(II)四水和物酢酸コバルト(Ⅱ)四水和物酢酸コバルト（II）?四水和物酢酸コバルト(Ⅱ)?四水和物酢酸コバルト(II)四水和物 ACS REAGENT,≥98.0%酢酸コバルト(II)四水和物 REAGENT GRADE酢酸コバルト(II) 四水和物酢酸コバルト( Ⅱ) 四水和物酢酸コバルト(II)四水和物, 98%酢酸コバルト(II)四水和物, 99.999% (metals basis)酢酸コバルト(II)四水和物, 98+%二酢酸コバルト(II)・四水和物二酢酸コバルト(II)・4水和物Cobalt diacetateACETIC ACID COBALT (II) SALT TETRAHYDRATECOBALT ACETATCobaltAcetateAroctankobaltnatyANTI-MOUSE LAMP-1ANTI-MOUSE CD107ACobalt acetate, GRCobalt tetrahydrate
Acetic acid, cobalt(+2) saltCobaltous diacetate tetrahydrateCobaltous acetate (tetrahydrate)DTXCID80132914612-153-6Cobalt(II) diacetateCobalt acetate tetrahydrateCobalt diacetate tetrahydrate
データベース識別子
- CAS
6147-53-1- PubChem CID
- 61372
- DTXSID
DTXSID80210423- UNII
- 7648Z91O1N
- EC Number
- 612-153-6
物性
構造計算による物性
- 極性表面積
- 84.3 Ų
- 水素結合供与体数
- 4
- 水素結合受容体数
- 8
- 回転可能結合数
- 0
- 重原子数
- 13
- 形式電荷
- 0
- 複雑度
- 25.5
実験および物理化学的性質
Chemical ClassesMetals -> Organic Acids, Metal Salts
Density1.7 g/cm³
SolubilitySolubility in water, g/100ml at 25 °C: (very good)
Melting Point140 °C
Physical Description
Dry Powder
Intense red solid; [Merck Index] Violet crystals, soluble in water; [MSDSonline] Delliquescent; [Ullmann]
RED CRYSTALS.
物理化学的性質
- 融点
- 140 °C · 140 °C
- 比重(密度)
- 1 · 1,71 g/cm3
- 屈折率
- 1.542 · 1.542
- 貯蔵温度
- 5 °C · Store at +5°C to +30°C.
- 溶解性
- 348 g/リットル · 348g/リットル
- 外見
- 個体
- 色
- 赤
- 比重
- 1.71 · 1.71
- 臭い (Odor)
- 酢酸臭
- PH
- 7.2 · 7.2 (50g/l, H2O, 20℃)
- 水溶解度
- 380 g/L · 380g/L(20℃)
- Merck
- 14 · 14,2433
- BRN
- 3731397 · 3731397
- 安定性
- 安定。湿気、熱を避けてください。
- InChI
- 1S/2C2H4O2.Co.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2
- InChIKey
- ZBYYWKJVSFHYJL-UHFFFAOYSA-L
- SMILES
- [H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Co]OC(C)=O
- CAS データベース
- 6147 · 6147-53-1(CAS DataBase Reference)
- EPAの化学物質情報
- Cobalt acetate tetrahydrate (6147-53-1)
化学的性質
化学的特性Reddish violet deliequecent crystals.
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]
P203, P233, P260, P261, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 2209 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H350: May cause cancer [Danger Carcinogenicity]
危険有害性情報
Regulatory Information
Chemical: Acetic acid, cobalt(2+) salt, tetrahydrate
Regulation (EC) No 1831/2003 (amended)
Acetic acid, cobalt(2+) salt, hydrate (2:1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Acetic acid, cobalt(2+) salt, hydrate (2:1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Cobalt (II) acetate tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard
Other Safety InformationIMAP assessments - Soluble cobalt (II) and salts: Human health tier II assessment
Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Hazards SummaryA skin, eye, and respiratory tract irritant; May cause skin sensitization; [ICSC] Harmful if swallowed; May cause skin and respiratory tract sensitization; [MSDSonline] See Cobalt.
Chemical DangersDecomposes on heating. This produces irritating fumes. Reacts with strong oxidants. This generates fire and explosion hazard.
Packaging and LabellingDo not transport with food and feedstuffs.
Hazard Classes and Categories
Skin Sens. 1 (100%)
Acute toxicity - category 4
Acute toxicity (Oral) - Category 4
Carcinogenicity - Category 1B
安全と保護具
Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures
Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Seek medical attention if you feel unwell.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
Safe StorageSeparated from strong oxidants. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
Exposure Control and Personal ProtectionBiological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Spillage Disposal
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations.
Eye PreventionWear safety goggles or eye protection in combination with breathing protection.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionPREVENT DISPERSION OF DUST! AVOID ALL CONTACT!
Ingestion PreventionDo not eat, drink, or smoke during work. Wash hands before eating.
Inhalation PreventionUse local exhaust or breathing protection.
Threshold Limit Values (TLV)0.02 [mg/m3], as Co
毒性情報
Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure RoutesThe substance can be absorbed into the body by inhalation and by ingestion.
Signs and Symptoms
Cough. Shortness of breath. Sore throat.
Redness.
Redness. Pain.
Abdominal pain. Nausea. Vomiting.
ICSC Environmental DataBioaccumulation of this chemical may occur in seafood.
安全データ
- wgk
- 2
- tsca
- No
- rtecs
- AG3325000
- ridadr
- 3077
- PRTR法
- 1-132
- hs_code
- 29152300
- risk_code
- 22-38-40-43-53-50/53-42/43-36/37/38-20/21/22-68-60-49
- 安衛法
- 特定化学物質障害予防規則:第2類物質,57,57-2
- hazard_code
- Xn,N,T
- safety_code
- 36/37-61-45-29-24-22-37/39-36/37/39-26-60-53
- hazard_class
- 9
- packing_group
- III
- Hazard Classifications
- Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 1B InhalationEye Irrit. 2Muta. 2Repr. 1BResp. Sens. 1Skin Sens. 1
- ストレージクラス
- 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
化学と産業
用途と製造
Uses
Used in sympathetic inks, feed additives, catalysts, foam stabilizers, driers for coatings, and anodizing; [Hawley]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
U.S. Production2023: <50,000 lb
Industry UsesCatalyst
General Manufacturing InformationPlastics Material and Resin Manufacturing
応用分野
用途ワニス塗料乾燥剤,ワニス原料,陶器顔料,液相酸化触媒,アルミニウム表面処理剤,医薬中間体 (NITE CHRIP)
用途塗料の乾燥剤、ワニスの原料
用途油溶性コバルト塩、触媒、医薬原料、顔料。
使用Cobalt(II) acetate tetrahydrate is used to prepare complexes for examination of the properties of metals with unusual coordination geometries. used as a catalyst for oxidation and esterification. used as an industrial catalyst to harden paints and varnishes, an active catalyst for oxidation and esterification reactions.
一般的な説明Cobalt(II) acetate tetrahydrate has an octahedral structure, the central cobalt orbit is coordinated by four water molecules and two acetate ligands. Cobalt(II) acetate tetrahydrate becomes anhydrous by 140oC.
調製方法
純化方法Several recrystallisations from 50% aqueous acetic acid give the tetrahydrate. It is converted to the anhydrous salt by drying at 80o/1mm for 60hours. [Beilstein 2 IV 120.]
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