フェニル尿素

Phenylurea

HCID 6145CAS 64-10-8
部分構造検索類似構造を探す

基本情報

標準SMILES
NC(=O)Nc1ccccc1
InChIKey
LUBJCRLGQSPQNN-UHFFFAOYSA-N
分子式
C7H8N2O
平均分子量
136.15 g/mol
単同位体質量
136.06366288

概要

Phenyl urea pesticide, liquid, poisonous appears as a liquid dissolved or suspended in a liquid carrier. Contains any of several related compounds (Diuron, Fenuron, Linuron, Neburon, Siduron, Monuron) formally derived from urea. Carrier is water emulsifiable. Toxic by inhalation, skin absorption, or ingestion. Obtain the technical name of the specific pesticide and carrier from the shipping papers and contact CHEMTREC, 800-424-9300 for response information.

名称と識別子

優先名称
Phenylurea
IUPAC
phenylurea
現地名
フェニル尿素
英語名
Phenylurea
分子式
C7H8N2O
分子量
136.15

名称と別名

1-PhenylureaPHENYLUREAN-Phenylurea64-10-8PhenylcarbamideMonophenylureaUrea, N-phenyl-amino-N-phenylamideDTXSID8042507NSC-2781862I85399WDTXCID6022507
名称をさらに表示
フェニル尿素安定剤VH(フェニルアミノ)ホルムアミド1-フェニル尿素スタビリサトールVHN-フェニル尿素フェニルカルバミドN1-フェニル尿素フェニル尿素, 97%VHphenyl-urestabilizervhUrea,phenyl-AKOS B029810
RefChem:164121200-576-5Urea, phenyl-Stabilizer VHStabilisator VHPhenyl-ureaphenyl ureaN-phenylcarbamimidic acid

データベース識別子

CAS
64-10-8
PubChem CID
6145
DTXSID
DTXSID8042507
ChEMBL
CHEMBL168445
ChEBI
CHEBI:180992
UNII
862I85399W
EC Number
200-576-5
Nikkaji
J4.834H

物性

構造計算による物性

XLogP
0.8
極性表面積
55.1 Ų
水素結合供与体数
2
水素結合受容体数
1
回転可能結合数
1
重原子数
10

実験および物理化学的性質

SpringerMaterials Properties15N nuclear magnetic resonance spectrum
Physical Description · 1 件

Phenyl urea pesticide, liquid, poisonous appears as a liquid dissolved or suspended in a liquid carrier. Contains any of several related compounds (Diuron, Fenuron, Linuron, Neburon, Siduron, Monuron) formally derived from urea. Carrier is water emulsifiable. Toxic by inhalation, skin absorption, or ingestion. Obtain the technical name of the specific pesticide and carrier from the shipping papers and contact CHEMTREC, 800-424-9300 for response information.

物理化学的性質

融点
145 · 145-147 °C(lit.)
沸点
238 °C · 238 °C
比重(密度)
1 · 1,302 g/cm3
蒸気密度
1 · >1 (vs air)
屈折率
1.5769 · 1.5769 (estimate)
闪点
238 °C · 238°C

化学的性質

化学的特性Colorless needle-like crystals or off-white powder. Melting point 147°C(decomposition), soluble in hot water, hot alcohol, ether, ethyl acetate and acetic acid.

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P264, P270, P301+P317, P330, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 3 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory Information · 2 件

Chemical: Urea, N-phenyl-

Phenylurea: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelPoison
Fire HazardsExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Health HazardsExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Reactive GroupAmides and Imides
Reactivity Profile · 1 件

Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). Contains any of several related compounds (Diuron, Fenuron, Linuron, Neburon, Siduron, Monuron) formally derived from urea.

安全と保護具

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
First AidExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

安全データ

wgk
3
tsca
TSCA listed
rtecs
YU0650000
毒性
LD50 oral in rat: 2gm/kg
hs_code
29242100
risk_code
22

化学と産業

用途と製造

General Manufacturing InformationUrea, N-phenyl-: ACTIVE
応用分野 · 2 件

使用Phenylureas are commonly used soil-applied herbicides for control of grass and small-seeded broadleaf weeds.

一般的な説明Phenylurea is the core structural unit of phenylurea herbicides (PUHs), such as diuron, fenuron, linuron, monuron, isoproturon, monolinuron and chlortoluron. As photosynthesis inhibitors, phenylurea herbicides are widely used in various crops for the pre-emergence and post-emergence control of broadleaf and annual weeds. These herbicides are used on major food crops, including maize (Zea mays) and tomato (Solanum lycopersicum), to control weeds such as lamb’s quarters (Chenopodium album), amaranth (Amaranthus spp.) and barnyard grass (Echinochloa crus-galli)[1].

調製方法 · 2 件

製造方法Phenylurea is synthesized by the reaction of aniline and urea. Put urea, hydrochloric acid and aniline into the reaction pot, heat and stir, reflux at 100-104°C for 1 hour, add water and stir, cool, filter, wash the filter cake with water, and dry to obtain the finished product of phenylurea.

純化方法Crystallise the urea from boiling water (10mL/g) or amyl alcohol (m 149o). Dry it in a steam oven at 100o. The 1:1 resorcinol complex has m 115o (from EtOAc/*C6H6). [Beilstein 12 H 346, 12 II 204, 12 III 760, 12 IV 734.]

上流・下流製品情報

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
淄博泰立泽化工有限公司0533-5200592 13173271895 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]

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