ホームMCPワークベンチSkills
ホームワークベンチ通知マイページ
llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
  1. ホーム
  2. /反応

Methacrylic Acid → Phenoxy ethylmethacrylate methylmethacrylate methacrylate

HRID 237166
ノート
印刷プレビュー

反応式

HRID 237166 の反応式
[CH2:1]([CH:3]=[C:4]([CH3:15])[C:5]([O:7][O:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)=[O:6])[CH3:2].[C:16]([OH:21])(=[O:20])[C:17]([CH3:19])=[CH2:18].[C:22]([O:27][CH3:28])(=[O:26])[C:23]([CH3:25])=[CH2:24]>C(C(C)=O)C.N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O>[CH2:1]([CH:3]=[C:4]([CH3:15])[C:5]([O:7][O:8][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)=[O:6])[CH3:2].[CH3:28][O:27][C:22](=[O:26])[C:23]([CH3:25])=[CH2:24].[C:16]([O-:21])(=[O:20])[C:17]([CH3:19])=[CH2:18]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

6

反応物 3

HCID 4093Methacrylic AcidHCID 6658Methyl MethacrylateHCID 86657890Phenoxy ethylmethacrylate

生成物 1

HCID 86657889Phenoxy ethylmethacrylate methylmethacrylate methacrylate収率 163.3%

試薬・触媒・溶媒 2

HCID 757631,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)触媒2 回
HCID 6569
Methyl Ethyl Ketone
溶媒
3 回

反応条件

温度
72 °C

実験手順

(Synthesis of Water-Insoluble Polymer Dispersant P-1) 88 g of methyl ethyl ketone was added to a 1000 ml three-necked flask equipped with an agitator and a condenser, and was heated to 72° C. under a nitrogen atmosphere. To this, a solution of 0.85 g of dimethyl 2,2′-azobisisobutyrate, 50 g of phenoxy ethylmethacrylate, 13 g of methacrylic acid and 37 g of methyl methacrylate dissolved in 50 g of methyl ethyl ketone was added dropwise over 3 hours. Once the dropwise addition was completed, the mixture was reacted for one more hour, and then a solution of 0.42 g of dimethyl 2,2′-azobisisobutyrate dissolved in 2 g of methyl ethyl ketone was added. The temperature was raised to 78° C., and the mixture was heated for 4 hours. The obtained reaction solution was precipitated two times in large excess of hexane, and the precipitated resin was dried to obtain 96.5 g of phenoxy ethylmethacrylate/methylmethacrylate/methacrylate (copolymerization ratio [% by mass ratio]=50/37/13) copolymer (resin dispersant P-1).

後処理

  1. customequipped with an agitator and a condenser
  2. additionwas added dropwise over 3 hours
  3. additionOnce the dropwise addition
  4. customthe mixture was reacted for one more hour
  5. additionwas added
  6. temperatureThe temperature was raised to 78° C.
  7. temperaturethe mixture was heated for 4 hours
  8. customThe obtained reaction solution
  9. customwas precipitated two times in large excess of hexane
  10. customthe precipitated resin was dried

出典と根拠

ORDレコード
ord-605f8938786442bf98d55b881050907d
出典データセット
uspto-grants-2014_02
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US08641181B2

反応ノート

読み込み中…

このページの内容参加物反応条件実験手順後処理出典と根拠反応ノート