CAS 1184-58-3 Chlorodimethylaluminum (HCID 79147)

名称と識別子

優先名称: Chlorodimethylaluminum
IUPAC: chloro(dimethyl)alumane
現地名: ジメチルアルミニウムクロリド
英語名: DIMETHYLALUMINUM CHLORIDE
分子式: C2H6AlCl
分子量: 92.5

名称と別名

Aluminum, chlorodimethyl-Dimethylaluminum chloride1184-58-3ChlorodimethylaluminumDimethylaluminium chlorideDTXSID5061580B548L3505QRefChem:134299DTXCID2033449214-668-8DimethylchloroaluminumAluminum,chlorodimethyl-

名称をさらに表示

ジメチルクロロアルミニウムジメチルアルミニウムクロリドクロロジメチルアルミニウム塩化ジメチルアルミニウム,N-ヘキサン溶液塩化ジメチルアルミニウム塩化ジメチルアルミニウム,N‐ヘキサン溶液ジメチルアルミニウムクロリド溶液塩化ジメチルアルミニウム,ヘプタン溶液,AcroSealＲDimethylaluminumDimethylchloralaneDimethylchloroalanechlorodimethyl-aluminuDimethylaluminiumchloridAluminiumdimethylchloride

chloro(dimethyl)alumaneUNII-B548L3505QEINECS 214-668-8Chlorodi(methyl)alumaneSCHEMBL5443Dimethylaluminum chloride, 97%AKOS009156843NS00081566

データベース識別子

CAS: 1184-58-3
PubChem CID: 79147
DTXSID: DTXSID5061580
EC Number: 214-668-8

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 0
重原子数: 4
形式電荷: 0
複雑度: 13

実験および物理化学的性質

Physical Description · 2 件

Liquid; CBI

White liquid; [Merck Index]

物理化学的性質

融点: -21 °C · -21°C
沸点: 126 · 126-127°C
比重(密度): 0.701 g/mL · 0.701 g/mL at 25 °C
蒸気圧: 79 mmHg · 79 mmHg ( 60 °C)
闪点: 1 °F · −1 °F
貯蔵温度: 0 · 0-6°C
溶解性: sol most organic solvents; stable in alkanes or arenes
外見: 液体
比重: 0.71 · 0.71
InChI: InChI=1S/2CH3.Al.ClH/h2*1H3;;1H/q;;+1;/p-1
InChIKey: JGHYBJVUQGTEEB-UHFFFAOYSA-M
SMILES: [Al](Cl)(C)C
EPAの化学物質情報: Aluminum, chlorodimethyl- (1184-58-3)

化学的性質

化学的特性Clear colorless liquid

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H225 (53.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]；H260 (100%): In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (53.5%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P210, P222, P223, P231, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 86 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 3 件

Chemical: Aluminium, chlorodimethyl-

Aluminum, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Aluminum, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Dimethylaluminium chloride: HSNO Approval: HSR006292 Approved with controls

Other Safety InformationIMAP assessments - Aluminium, chlorodimethyl-: Environment tier I assessment；IMAP assessments - Aluminium, chlorodimethyl-: Human health tier I assessment

Hazards Summary · 1 件

Reacts violently with water; Corrosive and pyrophoric; [Merck Index] Pyrophoric; Reacts violently with water evolving flammable gases; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Trimethylaluminum, Methyl aluminum sesquibromide, and Chlorodiethylaluminum.

Hazard Classes and CategoriesFlam. Liq. 2 (53.5%)；Pyr. Liq. 1 (100%)；Water-react. 1 (100%)；Skin Corr. 1B (100%)；Eye Dam. 1 (53.5%)

毒性情報

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

法規制情報

Regulatory Information · 3 件

Chemical: Aluminium, chlorodimethyl-

Aluminum, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Aluminum, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Dimethylaluminium chloride: HSNO Approval: HSR006292 Approved with controls

安全データ

wgk: 2
tsca: TSCA listed
ridadr: UN 3394 4.2/PG 1
PRTR法: 1-392
hs_code: 29319090
risk_code: 14/15-17-23/24/25-34-67-65-62-51/53-48/20-11
安衛法: 有機溶剤中毒予防規則:第2種有機溶剤,57,57-2
消防法: 危-3-OT-2-II
hazard_code: F,C,N
safety_code: 16-26-36/37/39-45-27-43-9
hazard_class: 4.2
packing_group: I

化学と産業

用途と製造

UsesUsed as a reagent and catalyst in organic chemistry; [Merck Index]

U.S. Production2023: 1,000,000 - <8,500,000 lb；2022: 1,000,000 - <8,500,000 lb；2021: 1,000,000 - <8,500,000 lb；2020: 1,000,000 - <8,500,000 lb

Industry UsesCBI；Catalyst

General Manufacturing Information · 2 件

CBI；Pesticide, Fertilizer, and Other Agricultural Chemical Manufacturing

Aluminum, chlorodimethyl-: ACTIVE

応用分野

使用Dimethylaluminum Chloride is used as a strong Lewis acid that can also act as a proton scavenger; reacts with HX to give methane and MeAlClX.

上流・下流製品情報

下流製品

イソプロピルマロン酸ジエチル塩化メチル水銀トリメチルガリウム 2-メチルベンゾ[b]チオフェン sec-ブチルマロン酸ジエチル

サプライヤー58 社

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]

杭州品高化工有限公司0571-87658025 · [email protected]

苏州市森菲达化工有限公司18796480002 18796480002 · [email protected]

化合物ノート

読み込み中…

ジメチルアルミニウムクロリド

基本情報