基本情報
- CAS
7393-43-3- 標準SMILES
C=C[CH2][Sn]([CH2]C=C)([CH2]C=C)[CH2]C=C- InChIKey
XJPKDRJZNZMJQM-UHFFFAOYSA-N- 分子式
- C12H20Sn
- 平均分子量
- 283 g/mol
- 単同位体質量
- 284.058703
名称と識別子
- 優先名称
- Tetrallylstannane
- IUPAC
- tetrakis(prop-2-enyl)stannane
- 現地名
- テトラアリルすず
- 英語名
- Tetraallyltin
- 分子式
- C12H20Sn
- 分子量
- 283
名称と別名
名称をさらに表示
データベース識別子
- CAS
7393-43-3- PubChem CID
- 81878
- DTXSID
DTXSID80224580- UNII
- 68PK869PUT
- EC Number
- 230-987-5
- Nikkaji
- J128.959D
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 8
- 重原子数
- 13
- 形式電荷
- 0
- 複雑度
- 146
物理化学的性質
- 沸点
- 69 · 69-70 °C1.5 mm Hg(lit.)
- 比重(密度)
- 1.179 g/mL · 1.179 g/mL at 25 °C(lit.)
- 屈折率
- 20 · n20/D 1.539(lit.)
- 闪点
- 167 °F · 167 °F
- 溶解性
- 2 O · sol common organic solvents; insol H2O.
- 外見
- 液体
- 比重
- 1.179 · 1.179
- 色
- 無色透明
- 水溶解度
- 水に溶けないか、混ざりにくい。
- BRN
- 3536269 · 3536269
- InChI
- 1S/4C3H5.Sn/c4*1-3-2;/h4*3H,1-2H2;
- InChIKey
- XJPKDRJZNZMJQM-UHFFFAOYSA-N
- SMILES
- C=CC[Sn](CC=C)(CC=C)CC=C
- CAS データベース
- 7393 · 7393-43-3(CAS DataBase Reference)
化学的性質
化学的特性Clear Colorless liquid
安全と法規制
GHS分類
GHS Classification
Danger
H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral];H311 (100%): Toxic in contact with skin [Danger Acute toxicity, dermal];H315 (66.7%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (66.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H330 (66.7%): Fatal if inhaled [Danger Acute toxicity, inhalation];H331 (33.3%): Toxic if inhaled [Danger Acute toxicity, inhalation];H400 (66.7%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (66.7%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P305+P351+P338, P316, P320, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 6 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
危険有害性情報
安全データ
- F
- 10-23
- wgk
- 3
- tsca
- No
- ridadr
- UN 2788 6.1/PG 3
- PRTR法
- 第一種指定化学物質
- hs_code
- 29310099
- risk_code
- 23/24/25
- 消防法
- 危-4-3-III
- hazard_code
- T
- safety_code
- 23-24/25-45-36/37
- hazard_class
- 6.1
- packing_group
- II
- ストレージクラス
- 10 - Combustible liquids
化学と産業
応用分野
使用Applied as allyl transfer reagent.
調製方法
製造方法Tetraallyltin is synthesized by the reaction of Allylmagnesium Bromide with Tin(IV) Chloride in THF.
純化方法Possible contaminants are allyl chloride and allyltin chloride. Check the 1H NMR and IR [Fishwick & Wallbridge J Organomet Chem 25 69 1970], and if impure, dissolve it in Et2O and shake it with a 5% aqueous solution of NaF which precipitates allyltin fluoride. Separate the Et2O layer, dry (MgSO4) and distil it at ~ 0.2mm. It decomposes slightly on repeated distillation. [O'Brien et al. Inorg Synth XIII 75 1972, Fishwick et al. J Chem Soc (A) 57 1971, Beilstein 4 III 1922.]
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