テトラアリルすず

Tetrallylstannane

HCID 81878

基本情報

CAS
7393-43-3
標準SMILES
C=C[CH2][Sn]([CH2]C=C)([CH2]C=C)[CH2]C=C
InChIKey
XJPKDRJZNZMJQM-UHFFFAOYSA-N
分子式
C12H20Sn
平均分子量
283 g/mol
単同位体質量
284.058703

名称と識別子

優先名称
Tetrallylstannane
IUPAC
tetrakis(prop-2-enyl)stannane
現地名
テトラアリルすず
英語名
Tetraallyltin
分子式
C12H20Sn
分子量
283

名称と別名

Tetraallyltin7393-43-3Tetrallylstannanetetrakis(prop-2-enyl)stannaneStannane, tetra-2-propenyl-EINECS 230-987-568PK869PUTAI3-28455DTXSID80224580TETRAKIS(2-PROPENYL)STANNANETETRA-2-PROPEN-1-YLSTANNANESTANNANE, TETRA-2-PROPEN-1-YL-
名称をさらに表示
テトラアリルすずテトラアリルすず(IV)テトラキス(2-プロペニル)スタンナンテトラアリルスタンナンテトラアリルすず, min. 95%テトラキス(プロパ-2-エン-1-イル)スタンナンSKL1137TETRAALLYLTIN(IV)Tetraallyltin 97%Tetraallyltin,97%Tetraallyltin, 95+%Tetraallyltin,min.95%
RefChem:897301DTXCID10147071230-987-5TetraallylstannaneStannane, tetraallyl-MFCD00008637TetraallylltinSn(allyl)4

データベース識別子

CAS
7393-43-3
PubChem CID
81878
DTXSID
DTXSID80224580
UNII
68PK869PUT
EC Number
230-987-5
Nikkaji
J128.959D

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
8
重原子数
13

物理化学的性質

沸点
69 · 69-70 °C1.5 mm Hg(lit.)
比重(密度)
1.179 g/mL · 1.179 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.539(lit.)
闪点
167 °F · 167 °F
溶解性
2 O · sol common organic solvents; insol H2O.
外見
液体

化学的性質

化学的特性Clear Colorless liquid

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral];H311 (100%): Toxic in contact with skin [Danger Acute toxicity, dermal];H315 (66.7%): Causes skin irritation [Warning Skin corrosion/irritation];H319 (66.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H330 (66.7%): Fatal if inhaled [Danger Acute toxicity, inhalation];H331 (33.3%): Toxic if inhaled [Danger Acute toxicity, inhalation];H400 (66.7%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (66.7%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P305+P351+P338, P316, P320, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 6 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazard Classes and CategoriesAcute Tox. 3 (100%);Acute Tox. 3 (100%);Acute Tox. 3 (33.3%)

安全データ

F
10-23
wgk
3
tsca
No
ridadr
UN 2788 6.1/PG 3
PRTR法
第一種指定化学物質
hs_code
29310099

化学と産業

応用分野

使用Applied as allyl transfer reagent.

調製方法 · 2 件

製造方法Tetraallyltin is synthesized by the reaction of Allylmagnesium Bromide with Tin(IV) Chloride in THF.

純化方法Possible contaminants are allyl chloride and allyltin chloride. Check the 1H NMR and IR [Fishwick & Wallbridge J Organomet Chem 25 69 1970], and if impure, dissolve it in Et2O and shake it with a 5% aqueous solution of NaF which precipitates allyltin fluoride. Separate the Et2O layer, dry (MgSO4) and distil it at ~ 0.2mm. It decomposes slightly on repeated distillation. [O'Brien et al. Inorg Synth XIII 75 1972, Fishwick et al. J Chem Soc (A) 57 1971, Beilstein 4 III 1922.]

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
Henan Rane Chemical Co., Ltd.+86-18738066252 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]

関連反応

5 件

化合物ノート

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