2,2'-Azobis(2-methylbutyronitrile) (HCID 93079)

概要

2,2'-azodi-(2-methylbutyronitrile) appears as an odorless white powdered solid. May burst into flames upon exposure to fire or high heat. Dust may form an explosive mixture in air.

名称と識別子

優先名称: 2,2'-Azobis(2-methylbutyronitrile)
IUPAC: 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile
現地名: 2,2'-アゾビス(2-メチルブチロニトリル)
英語名: 2,2'-Azodi(2-methylbutyronitrile)
分子式: C10H16N4
分子量: 192.26

名称と別名

13472-08-72,2'-Azobis(2-methylbutyronitrile)2,2'-Azobis(2-methylbutanenitrile)Butanenitrile, 2,2'-azobis[2-methyl-DTXSID8027747Butanenitrile, 2,2'-azobis(2-methyl-5DCY6GCZ6V2,2'-azobis[2-methylbutyronitrile]EINECS 236-740-82,2'-azobis(2-cyanobutane)Butyronitrile, 2,2'-azobis(2-methyl-EC 236-740-8

名称をさらに表示

2,2'-アゾビス(2-メチルブチロニトリル)2,2'-アゾビス(2-メチルブタンニトリル)2,2'-アゾジ(2-メチルブチロニトリル)２，２’－アゾビス（２－メチルブチロニトリル）2.2'-アゾビス(2-メチルブチロニトリル)アゾビスメチルブチロニトリル２，２’アゾビス（２メチルブチロニトリル）2,2′-アゾジ(2-メチルブチロニトリル)2,2′-アゾビス(2-メチルブタンニトリル)2,2′-アゾビス(2-メチルブチロニトリル)2-[2-(1-シアノ-1-メチルプロピル)ジアゼン-1-イル]-2-メチルブタンニトリル1,2-ビス(1-シアノ-1-メチルプロピル)ジアゼン2,2'-ｱｿﾞﾋﾞｽ[2-ﾒﾁﾙﾌﾞﾀﾝﾆﾄﾘﾙ]AMBNv59butyronitriLABMNVAZO6vazo6799.18%AMBM-67vazo64-a

2,2'-Azobis[2-methylbutanenitrile]Butanenitrile, 2,2'-(1,2-diazenediyl)bis(2-methyl-2,2'-dimethyl-2,2'-azodibutyronitrile2,2'-AZOBIS(.ALPHA.-METHYLBUTYRONITRILE)2,2'-(1,2-DIAZENEDIYL)BIS(2-METHYLBUTANENITRILE)Butanenitrile, 2,2'-(1,2-diazenediyl)bis[2-methyl-RefChem:440196DTXCID00809994

データベース識別子

CAS: 13472-08-7
PubChem CID: 93079
DTXSID: DTXSID8027747
ChEMBL: CHEMBL3182601
UNII: 5DCY6GCZ6V
EC Number: 236-740-8
Nikkaji: J248.387D

物性

構造計算による物性

XLogP: 2.4
極性表面積: 72.3 Å²
水素結合供与体数: 0
水素結合受容体数: 4
回転可能結合数: 4
重原子数: 14
形式電荷: 0
複雑度: 284

実験および物理化学的性質

Physical Description · 2 件

2,2'-azodi-(2-methylbutyronitrile) appears as an odorless white powdered solid. May burst into flames upon exposure to fire or high heat. Dust may form an explosive mixture in air.

Large Crystals; CBI

物理化学的性質

融点: 49 · 49-52 °C
沸点: 318.25 °C · 318.25°C (rough estimate)
比重(密度): 1.1 · 1.1
蒸気圧: 0.354 Pa · 0.354Pa at 25℃
屈折率: 1.491 · 1.4910 (estimate)
貯蔵温度: 2 · 2-8°C
溶解性: クロロホルム（少量）、メタノール（少量）
外見: 個体
色: ホワイトからオフホワイト
水溶解度: 392 mg/L · 392mg/L at 20℃
Henry's Law Constant: 4.5 · 4.5×104 mol/(m3Pa) at 25℃, Zhang et al. (2010)
安定性: 爆発的な。ぶつけたり、接地したり、加熱したりすると、爆発する危険性があります。とても燃えやすい。強力な酸化剤とは相容れない。
InChI: InChI=1S/C10H16N4/c1-5-9(3,7-11)13-14-10(4,6-2)8-12/h5-6H2,1-4H3
InChIKey: AVTLBBWTUPQRAY-UHFFFAOYSA-N
SMILES: N(C(C)(CC)C#N)=NC(C)(CC)C#N
LogP: 2.07 at · 2.07 at 20℃
CAS データベース: 13472 · 13472-08-7(CAS DataBase Reference)
EPAの化学物質情報: 2 · 2,2'-Azobis[2-methylbutanenitrile] (13472-08-7)

化学的性質

化学的特性solid

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 0.6% (6 of 990) of reports.

Danger

H225 (17.8%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P234, P235, P240, P241, P242, P243, P264, P270, P273, P280, P301+P317, P303+P361+P353, P330, P370+P378, P403, P403+P235, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 990 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 5 件

Chemical: Butanenitrile, 2,2'-azobis[2-methyl-

Butanenitrile, 2,2'-(1,2-diazenediyl)bis[2-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butanenitrile, 2,2'-(1,2-diazenediyl)bis[2-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 08-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5486

Butanenitrile, 2-methyl, 2,2 azorbis: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Butanenitrile, 2,2'-azobis[2-methyl-: Human health tier I assessment

DOT LabelFlammable Solid

Fire HazardsExcerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

Health HazardsExcerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

Reactive GroupAzo, Diazo, Azido, Hydrazine, and Azide Compounds

安全と保護具

Fire FightingExcerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

First AidExcerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

Nonfire Spill ResponseExcerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

Isolation and EvacuationExcerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 150 [Substances (Self-Reactive / Temperature Controlled)]:

安全データ

F: 4.4
wgk: 1
tsca: TSCA listed
rtecs: EK4818750
ridadr: UN 3236 4.1
毒性: LD50 orl-rat: 982 mg/kg NTIS** OTS0540633
hs_code: 29270000
risk_code: 11-22-2017/11/22
化審法: (2)-3539
消防法: 危-5-II
hazard_code: F,Xn
safety_code: 47-36/37/39-24/25-16
hazard_class: 4.1
packing_group: II
毒劇物取締法: 劇物

化学と産業

用途と製造

U.S. Production2023: 1,000,000 - <8,500,000 lb

Industry UsesChain transfer agent

General Manufacturing Information · 2 件

Plastics Material and Resin Manufacturing

Butanenitrile, 2,2'-(1,2-diazenediyl)bis[2-methyl-: ACTIVE

応用分野

用途重合開始剤。

上流・下流製品情報

上流原料

抱水ヒドラジンシアン化ナトリウム 2-アミノ-2-メチルブタンニトリル

サプライヤー50 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

江西益众化工有限公司15307925109 15350027073 · [email protected]

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

淄博浩一环保科技有限公司15689319914 · [email protected]

2,2'-アゾビス(2-メチルブチロニトリル)

基本情報

概要