Sodium Hydroxide → 2,2'-Azobis(2-methylbutyronitrile)

HRID 464114

反応式

HRID 464114 の反応式
[OH-].[Na+].[NH2:3][C:4]([CH3:9])([CH2:7][CH3:8])[C:5]#[N:6]>CCCCCCCCCCCCCCCC[N+](C)(C)C.[Cl-]>[N:3]([C:4]([CH3:9])([CH2:7][CH3:8])[C:5]#[N:6])=[N:3][C:4]([CH3:9])([CH2:7][CH3:8])[C:5]#[N:6]

参加物

4

反応物 2

HCID 14798Sodium Hydroxide2 回HCID 155768302-Amino-2-methyl-butyronitrile

生成物 1

HCID 930792,2'-Azobis(2-methylbutyronitrile)収率 173.8%

試薬・触媒・溶媒 1

HCID 8154Hexadecyltrimethylammonium chloride触媒

反応条件

温度
20 °C

実験手順

The resulting aqueous dispersion of N,N-dichloro-2-amino-2-methylbutanenitrile was adjusted to pH7 by the addition of caustic soda and 3 ml of "Arquad 16-29%" surfactant added. After addition of a further 2.2 equivalents of caustic soda, 16.8 gm of 2-amino-2-methylbutanenitrile were added slowly over 60 minutes whilst maintaining the temperature at 20° C. The resulting suspension was filtered, washed and dried to yield 28.6 gm of the title compound (yield 84.2%).

後処理

  1. additionadded
  2. additionwere added slowly over 60 minutes
  3. filtrationThe resulting suspension was filtered
  4. washwashed
  5. customdried

出典と根拠

ORDレコード
ord-53d103c42b304bc9a113775e85116898
出典データセット
uspto-grants-1985_10
特許番号
US04546174

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