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リチウム·ヘキサフルオロアルセナート(V)

Lithium hexafluoroarsenate

HCID 9837036
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基本情報名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
29935-35-1
標準SMILES
F[As-](F)(F)(F)(F)F.[Li+]
InChIKey
GTZQZEYBOGZTEO-UHFFFAOYSA-N
分子式
AsF6Li
平均分子量
195.9 g/mol
単同位体質量
195.928017

名称と識別子

優先名称
Lithium hexafluoroarsenate
IUPAC
lithium hexafluoroarsenic(1-)
現地名
リチウム·ヘキサフルオロアルセナート(V)
英語名
Lithium hexafluoroarsenate(V)
分子式
AsF6.Li
分子量
195.85

名称と別名

Lithium hexafluoroarsenate29935-35-1Arsenate(1-), hexafluoro-, lithiumArsenate(1-), hexafluoro-, lithium (1:1)DTXSID50885465LiAsF6RefChem:799547DTXCID501024844249-963-0Lithium hexafluoroarsenate(V)lithium;hexafluoroarsenic(1-)MFCD00011076
名称をさらに表示
リチウム·ヘキサフルオロアルセナート(V)ヘキサフルオロアルセナート(V)·リチウムヘキサフルオロひ酸(V)リチウムヘキサフルオロヒ酸リチウム6弗化砒酸リチウム六フッ化ヒ酸リチウム六フッ化砒酸リチウムithium hexafLuoroarsenate(V)lithium:hexafluoroarsenic(1-)Hexafluoroarsenate(V)·lithiumhexafluoro-arsenate(1-lithiumLithiumhexafluoroarsenate(V),99%Lithium hexafluoroarsenate(V),98%
lithium hexafluoroarsoranuide3-Butyn-1-amineHydrochlorideAsF6LiSCHEMBL156146Lithium hexafluoridoarsenate(1-)LITHIUMHEXAFLUOROARSENATE(V)SBB091935SY074767

データベース識別子

CAS
29935-35-1
PubChem CID
9837036
DTXSID
DTXSID50885465
EC Number
249-963-0

物性

構造計算による物性補完中

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
7
回転可能結合数
0
重原子数
8
形式電荷
0
複雑度
62

実験および物理化学的性質

Physical DescriptionWhite, odorless, hygroscopic powder; Soluble in water; [Alfa Aesar MSDS]

物理化学的性質

融点
349 °C · 349°C
外見
粉
色
白い
水溶解度
水に不溶。
安定性
安定。強力な酸化剤とは相容れない。
主な用途
電池前駆体触媒材料合成前駆体
InChI
InChI=1S/AsF6.Li/c2-1(3,4,5,6)7;/q-1;+1
InChIKey
GTZQZEYBOGZTEO-UHFFFAOYSA-N
SMILES
[As+5]([F-])([F-])([F-])([F-])([F-])[F-].[Li+]
CAS データベース
29935 · 29935-35-1(CAS DataBase Reference)
EPAの化学物質情報
Arsenate(1-), hexafluoro-, lithium (29935-35-1)

化学的性質

化学的特性white powder

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 0.7% (1 of 151) of reports.

Danger

H301+H331 (69.5%): Toxic if swallowed or if inhaled [Danger Acute toxicity, oral; acute toxicity, inhalation];H301 (99.3%): Toxic if swallowed [Danger Acute toxicity, oral];H331 (98.7%): Toxic if inhaled [Danger Acute toxicity, inhalation];H350 (69.5%): May cause cancer [Danger Carcinogenicity];H400 (96%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (98%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P203, P261, P264, P270, P271, P273, P280, P301+P316, P304+P340, P316, P318, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 151 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 1 of 151 reports by companies.;There are 7 notifications provided by 150 of 151 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 2 件

Restricted substance: Lithium hexafluoroarsenate;EC: 249-963-0;Restriction condition document: PDF link

Lithium hexafluoroarsenate: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryAn irritant; Toxic by ingestion and inhalation; [Alfa Aesar MSDS] See Arsenic and the linked occupational diseases.
Hazard Classes and Categories · 4 件

化学と産業

用途と製造

General Manufacturing InformationArsenate(1-), hexafluoro-, lithium (1:1): ACTIVE

応用分野

使用Lithium hexafluoroarsenate(V) is a potential battery electrolyte material.

一般的な説明This product has been enhanced for energy efficiency.

上流・下流製品情報

上流原料

ポリエチレンリチウムヒドロキシド

関連反応

3 件
反応記録を作成
HRID 254897 の反応式
HRID 254897反応物としてuspto-grants-2011_01
HRID 254900 の反応式
HRID 254900反応物としてuspto-grants-2011_01
HRID 254903 の反応式
HRID 254903反応物としてuspto-grants-2011_01

化合物ノート

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その他の操作
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Acute Tox. 3 (99.3%);Acute Tox. 3 (98.7%);Carc. 1A (69.5%);Aquatic Acute 1 (96%);Aquatic Chronic 1 (98%)

Serious eye damage/eye irritation - Category 2;Carcinogenicity - Category 1A;Reproductive toxicity - Category 2;Specific target organ toxicity - Single exposure - Category 1 (digestive system, circulatory system, nervous system, blood system, respiratory system, skin, kidney, liver);Specific target organ toxicity - Repeated exposure - Category 1 (digestive system, circulatory system, nervous system, kidney, liver, blood system, respiratory system, skin, skeletal system)

Serious eye damage/eye irritation - Category 2B;Carcinogenicity - Category 1A;Reproductive toxicity - Category 1A;Specific target organ toxicity - Single exposure - Category 1 (digestive system, cardiovascular system, nervous system, kidney, liver, respiratory system);Specific target organ toxicity - Repeated exposure - Category 1 (digestive system, cardiovascular system, nervous system, kidney, liver, blood system, skin, respiratory system, bone)

Reproductive toxicity - Category 1A, Additional category: Effects on or via lactation;Specific target organ toxicity - Single exposure - Category 1 (nervous system), Category 3 (narcotic effects);Specific target organ toxicity - Repeated exposure - Category 1 (nervous system)

安全と保護具

Exposure Control and Personal ProtectionBiological Exposure Indices (BEI) [ACGIH] - Inorganic arsenic plus methylated metabolites in urine = 35 ug As/L; end of workweek;
Threshold Limit Values (TLV)0.01 [mg/m3], as As
Permissible Exposure Limit (PEL)0.01 [mg/m3], as As
Immediately Dangerous to Life or Health (IDLH)5.0 [mg/m3], as As

毒性情報

Adverse Effects · 1 件

Neurotoxin - Sensorimotor;Occupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.;Aplastic anemia - The presence of increased methemoglobin in the blood; the compound is classified as primary toxic effect.;Reproductive Toxin - A chemical that is toxic to the reproductive system, including defects in the progeny and injury to male or female reproductive function. Reproductive toxicity includes developmental effects. See Guidelines for Reproductive Toxicity Risk Assessment.;IARC Carcinogen - Class 1: International Agency for Research on Cancer classifies chemicals as established human carcinogens.;NTP Carcinogen - Known to be a human carcinogen.;ACGIH Carcinogen - Confirmed Human.

法規制情報

Regulatory Information · 2 件

Restricted substance: Lithium hexafluoroarsenate;EC: 249-963-0;Restriction condition document: PDF link

Lithium hexafluoroarsenate: Does not have an individual approval but may be used under an appropriate group standard

安全データ

F
10
wgk
3
tsca
TSCA listed
ridadr
UN 1557 6.1/PG 2
hs_code
28269080
risk_code
23/25-50/53
hazard_code
T,N
hazard_note
Toxic
safety_code
20/21-28-45-60-61
hazard_class
6.1
packing_group
II
Hazard Classifications
Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1
ストレージクラス
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects