Tetrahydrofuran → methyl 2,3-dimethyl-3,4-dihydro-1H-isoquinoline-6-carboxylate

反応式

[CH2:31]1[O:32][CH2:33][CH2:34][CH2:35]1.[CH3:1][N:2]1[C:3](=[O:17])[c:4]2[cH:5][cH:6][c:7]([C:13](=[O:14])[O:15][CH3:16])[cH:8][c:9]2[CH2:10][CH:11]1[CH3:12].[c:18]1([SiH2:19][c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[cH:26][cH:27][cH:28][cH:29][cH:30]1>>[CH3:1][N:2]1[CH2:3][c:4]2[cH:5][cH:6][c:7]([C:13](=[O:14])[O:15][CH3:16])[cH:8][c:9]2[CH2:10][CH:11]1[CH3:12]

参加物

反応物 3

HCID 8028Tetrahydrofuran

HCID 69888Diphenylsilane

HCID 90985117Methyl 2,3-dimethyl-1-oxo-3,4-dihydroisoquinoline-6-carboxylate

生成物 1

HCID 91361454methyl 2,3-dimethyl-3,4-dihydro-1H-isoquinoline-6-carboxylate

出典と根拠

ORDレコード: ord-5df64d42ecc149cd96079a20e5c02cc2
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…