Platinum → Platinum divinyltetramethyldisiloxane

HRID 1004726

反応式

HRID 1004726 の反応式
[H+].[H+].Cl[Pt-2:4](Cl)(Cl)(Cl)(Cl)Cl.[C:10](=O)(O)[O-].[Na+].[CH:15]([Si:17]([CH3:25])([CH3:24])[O:18][Si:19]([CH3:23])([CH3:22])[CH:20]=[CH2:21])=C.[Pt]>C(O)(C)C>[Pt:4].[CH:22]([Si:19]([CH:20]=[CH2:21])([CH3:23])[O:18][Si:17]([CH3:25])([CH3:24])[CH3:15])=[CH2:10]

参加物

6

反応物 4

HCID 23939PlatinumHCID 61859Chloroplatinic acidHCID 758191,3-Divinyltetramethyldisiloxane2 回HCID 516892Sodium Bicarbonate

生成物 1

HCID 86614225Platinum divinyltetramethyldisiloxane

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

実験手順

3.0 kg chloroplatinic acid crystals (40% platinum content) and 15.0 kg isopropanol were placed in a 50-L reactor, and 6.0 kg sodium bicarbonate and 6.0 kg 1,3-divinyltetramethyldisiloxane were then added while stirring. The resulting suspension was heated while stirring. After reacting for 30 minutes at 65 to 75° C., the reaction mass was cooled and the solids were filtered off to give 22.0 kg of an isopropanol solution of platinum-divinyltetramethyldisiloxane complex catalyst. The platinum content was 4.1% as measured by x-ray fluorescence analysis, and the 1,3-divinyltetramethyldisiloxane content as measured by gas chromatography was 9.4%.

後処理

  1. temperatureThe resulting suspension was heated
  2. stirringwhile stirring
  3. temperaturethe reaction mass was cooled
  4. filtrationthe solids were filtered off
  5. customto give 22.0 kg of an isopropanol solution of platinum-divinyltetramethyldisiloxane complex catalyst

出典と根拠

ORDレコード
ord-84a50968e75d4a598a449d5a46f18388
出典データセット
uspto-grants-2000_04
特許番号
US06051673

関連ノート

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