Ethylbenzene → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 1005429

反応式

HRID 1005429 の反応式
[C:1](#[N:4])[CH:2]=[CH2:3].[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.C(C1C=CC=CC=1)C.C(=O)([O-])OC(OOC(C)(C)C)(C)C>>[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.[C:1](#[N:4])[CH:2]=[CH2:3]

参加物

5

反応物 4

HCID 7500EthylbenzeneHCID 7501StyreneHCID 7855AcrylonitrileHCID 86748635t-Butylperoxyisopropyl carbonate

生成物 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)

実験手順

A liquid mixture consisting of 4.7 parts by weight of acrylonitrile, 73.3 parts by weight of styrene, 22 parts by weight of ethylbenzene and 0.02 parts by weight of t-butylperoxy-isopropyl carbonate employed as a polymerization initiator was supplied continuously into a complete mixing-type reactor (capacity: 5 liter) at a flow rate of 2.5 liter/hr and polymerization was performed at 142° C. until the degree of polymerization reached 60%. Then the polymer solution was fed continuously into a vent-type extruder where the unreacted monomers and the solvent were removed therefrom at 260° C. and 40 Torr. Next, the polymer was continuously solidified by cooling and cut into pieces to give a particulate styrene/acrylonitrile copolymer (referred to as AS-1). When analyzed by IR absorption spectrometry, this copolymer was composed of 9% by weight of the acrylonitrile unit and 91% by weight of the styrene unit and had a melt flow rate of 90 g/10 min (measured at 220° C. with a load of 10 kg in accordance with ASTM D-1238). This copolymer is referred to as AS-1 hereinafter.

後処理

  1. customwas supplied continuously into a complete mixing-type reactor
  2. custom(capacity: 5 liter) at a flow rate of 2.5 liter/hr and polymerization
  3. customwas performed at 142° C. until the degree of polymerization
  4. customthe solvent were removed
  5. customat 260° C.
  6. temperatureby cooling

出典と根拠

ORDレコード
ord-07d2697148e54dd5b51378cbe3c62f37
出典データセット
uspto-grants-2000_04
特許番号
US06054516

関連ノート

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