Ammonia → 2,6-Lutidine

HRID 1012370

反応式

HRID 1012370 の反応式
N.[BH3:2].C([N:5]([CH2:12][CH3:13])[C:6]1[CH:11]=[CH:10][CH:9]=C[CH:7]=1)C.B.[C:15]1([N:21]2[CH2:26][CH2:25][O:24][CH2:23][CH2:22]2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.B.[N:28]1C(C)=CC=CC=1C>>[C:15]1([N:21]2[CH2:26][CH2:25][O:24][CH2:23][CH2:22]2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[N:5]1[C:6]([CH3:7])=[CH:11][CH:10]=[CH:9][C:12]=1[CH3:13].[NH3:28].[BH3:2]

参加物

7

反応物 4

HCID 222Ammonia2 回HCID 83312Diethylaniline-boraneHCID 15265529(T-4)-Trihydro(4-phenylmorpholine-kappaN4)boronHCID 178419164HCID 178419164、化合物

生成物 3

HCID 79372,6-LutidineHCID 623394-PhenylmorpholineHCID 419330Ammonia;borane

実験手順

For example, dimethylaniline borane can be reacted with ammonia to produce ammonia borane as shown below. (C6H5)(CH3)2N.BH3+NH3=(C6H5)(CH3)2N+NH3.BH3 In other examples, diethylaniline borane, phenylmorpholine borane or lutidine borane can be reacted with ammonia to form ditethylaniline and ammonia borane, phenylmorpholine and ammonia borane, or lutidine and ammonia borane.

出典と根拠

ORDレコード
ord-889a1419970e4c178f8797f81dee20b9
出典データセット
uspto-grants-2011_07
特許番号
US07977508B2

関連ノート

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