Azide → 1-Amino-3-acetoxy acetone

HRID 1032359

反応式

HRID 1032359 の反応式
[N:1]([CH2:4][C:5]([CH2:7][O:8][C:9](=[O:11])[CH3:10])=[O:6])=[N+]=[N-].[N-]=[N+]=[N-]>C(OC(=O)C)C.[Pd]>[NH2:1][CH2:4][C:5]([CH2:7][O:8][C:9](=[O:11])[CH3:10])=[O:6]

参加物

5

反応物 2

HCID 33558AzideHCID 144347801-Azido-3-acetoxyacetone

生成物 1

HCID 221655021-Amino-3-acetoxy acetone

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 8857Ethyl Acetate溶媒

実験手順

1-Azido-3-acetoxyacetone (15.7 g.) is dissolved in ethylacetate (200 ml.). The 10% palladium on carbon catalyst (1.0 g.) is added; the mixture is reduced under hydrogen at atmospheric pressure until the infrared spectrum of an aliquot indicates the absence of the azide. The catalyst is filtered off and the filtrate is evaporated to afford 1-amino-3-acetoxy acetone.

後処理

  1. filtrationThe catalyst is filtered off
  2. customthe filtrate is evaporated

出典と根拠

ORDレコード
ord-d78563e8c20a42e683058c62180c6b7d
出典データセット
uspto-grants-1990_09
特許番号
US04957912

関連ノート

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