a Farnesol → 3,7,11-Trimethyl-1-dodecanol

HRID 1037499

反応式

HRID 1037499 の反応式
[OH:1][CH2:2][CH:3]=[C:4]([CH2:6][CH2:7][CH:8]=[C:9]([CH2:11][CH2:12][CH:13]=[C:14]([CH3:16])[CH3:15])[CH3:10])[CH3:5]>CO.[Pt]>[CH3:5][CH:4]([CH2:6][CH2:7][CH2:8][CH:9]([CH3:10])[CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])[CH2:3][CH2:2][OH:1]

参加物

4

反応物 1

HCID 3327a Farnesol

生成物 1

HCID 1388243,7,11-Trimethyl-1-dodecanol

試薬・触媒・溶媒 2

HCID 23939Platinum触媒2 回HCID 887Methanol溶媒

実験手順

Farnesol (3.00 g, 13.5 mmol) was dissolved in methanol (30 ml), Pt/C (2%, 0.30 g) was suspended therein and the suspension was stirred overnight under a hydrogen atmosphere. After completion of the reaction, Pt/C was removed by filtration, and the filtrate was concentrated to give 3,7,11-trimethyldodecan-1-ol. This was used for the next reaction without purification.

後処理

  1. customwas removed by filtration
  2. concentrationthe filtrate was concentrated

出典と根拠

ORDレコード
ord-d1255acebb554292964336f0e0b2f587
出典データセット
uspto-grants-2013_10
特許番号
US08546534B2

関連ノート

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