Hydrogen Sulfide → Bis dodecyl phenol sulphide

HRID 1076008

反応式

HRID 1076008 の反応式
[CH2:1]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[S].[OH-].[Na+].[SH2:23]>>[CH2:10]([C:18]1[C:13]2([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[S:23][C:14]2([OH:19])[CH:15]=[CH:16][CH:17]=1)[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][CH2:13][CH3:14]

参加物

5

反応物 4

HCID 402Hydrogen SulfideHCID 14798Sodium Hydroxide2 回HCID 1711442-DodecylphenolHCID 5362487Sulfur

生成物 1

HCID 86733380Bis dodecyl phenol sulphide

実験手順

A mixture of dodecyl phenol (1.0m., 262g.), sulphur (1.0m., 32g.) and caustic soda (8g.) was heated, with stirring, under nitrogen, at 160° C until the evolution of hydrogen sulphide ceased (42 hrs.). The caustic soda was neutralized with 10 ml. of phosphoric acid (SG = 1.75) and the mixture was then filtered. %S of Product = 5.85 (calc. = 5.8).

後処理

  1. temperaturewas heated
  2. custom(42 hrs.)
  3. filtrationof phosphoric acid (SG = 1.75) and the mixture was then filtered

出典と根拠

ORDレコード
ord-cab618fac034433f919109032ac0567e
出典データセット
uspto-grants-1976_05
特許番号
US03954808

関連ノート

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