N-vinyl-2-pyrrolidone → Isooctyl Acrylate N-vinyl-2-pyrrolidone

HRID 1081223

反応式

HRID 1081223 の反応式
[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[CH:14]([N:16]1[CH2:20][CH2:19][CH2:18][C:17]1=[O:21])=[CH2:15].CCCCCCC>C(OCC)(=O)C>[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[CH:14]([N:16]1[CH2:20][CH2:19][CH2:18][C:17]1=[O:21])=[CH2:15]

参加物

5

反応物 3

HCID 6917N-vinyl-2-pyrrolidoneHCID 8900HeptaneHCID 165746Isooctyl acrylate

生成物 1

HCID 44150239Isooctyl Acrylate N-vinyl-2-pyrrolidone

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒2 回

反応条件

温度
55 °C

実験手順

Isooctyl acrylate (54.9 Kg), N-vinyl-2-pyrrolidone (5.4 Kg), and ethyl acetate (93.6 Kg) were charged into a 75 gallon (285 liter) stainless steel reactor. The mixture was deoxygenated and heated to 55° C. After 5 minutes at 55° C., azobisisobutyronitrile (30 g) premixed in ethyl acetate (1 Kg) was charged to the reactor. Additional portions of azobisisobutyronitrile (30 g) premixed with ethyl acetate (1 Kg) were added 4 hours after the start of the reaction and again at 8 hours. The temperature was maintained at 55° C. throughout the reaction. The reaction was continued until complete. An antioxidant (61 g, IRGANOX™ 1010, Ciba-Geigy Corp.) and heptane (66.3 Kg) were added to the reactor and the contents mixed until homogeneous. The final copolymer had a measured inherent viscosity of 1.67 deciliter/g in ethyl acetate.

後処理

  1. customThe mixture was deoxygenated
  2. additionazobisisobutyronitrile (30 g) premixed in ethyl acetate (1 Kg)
  3. additionwas charged to the reactor
  4. additionAdditional portions of azobisisobutyronitrile (30 g) premixed with ethyl acetate (1 Kg)
  5. additionwere added 4 hours
  6. customafter the start of the reaction
  7. waitagain at 8 hours
  8. temperatureThe temperature was maintained at 55° C. throughout the reaction
  9. additionthe contents mixed until homogeneous

出典と根拠

ORDレコード
ord-31f64f604f5f4248a32fa774bf29c4a0
出典データセット
uspto-grants-1996_12
特許番号
US05585111

関連ノート

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