反応式
[CH3:1][C:2]1[C:9]([N+:10]([O-])=O)=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][OH:5]>C(O)C.[Pd]>[NH2:10][C:9]1[C:2]([CH3:1])=[C:3]([CH:6]=[CH:7][CH:8]=1)[CH2:4][OH:5]参加物
4
実験手順
A solution of 2-methyl-3-nitrobenzyl alcohol (2.0 g, 12 mmol) in ethanol (100 ml) was hydrogenated over 10% palladium/charcoal (0.1 g) for 2 hours, at an initial pressure of 3.5 bar. The solution was filtered through celite and evaporated to give 3-amino-2-methylbenzyl alcohol (1.67 g, quantitative), m.p. 104°-106°
後処理
- filtrationThe solution was filtered through celite
- customevaporated
出典と根拠
- ORDレコード
- ord-964ca6295eb64af1ac47407e4136b9c0
- 出典データセット
- uspto-grants-1992_01
- 特許番号
- US05082848
関連ノート
読み込み中…