Chlorotrimethylsilane → 1-Chloro-3,7-dimethyl-octa-2,6-diene

HRID 1169177ノート

反応式

HRID 1169177 の反応式
[CH2:1]=[CH:2][C:3]([CH2:6][CH2:7][CH:8]=[C:9]([CH3:11])[CH3:10])([CH3:5])O.C[Si](C)(C)[Cl:14]>[Bi+]=O>[Cl:14][CH2:1][CH:2]=[C:3]([CH3:5])[CH2:6][CH2:7][CH:8]=[C:9]([CH3:11])[CH3:10]

参加物

4

反応物 2

HCID 6397ChlorotrimethylsilaneHCID 6549Linalool

生成物 1

HCID 991061-Chloro-3,7-dimethyl-octa-2,6-diene収率 83.2%

試薬・触媒・溶媒 1

HCID 5237718Bismuthyl (ion)触媒

反応条件

温度
60 °C

実験手順

To a mixture of 170 g linalool and 20 mg bismuth(III)-oxide heated to 60° C., 130.5 g trimethylchlorosilane were added. Then, the mixture was cooled to room temperature and the organic layer was separated. The resulting oil was purified by distillation to yield 158.35 g of a colorless oil.

後処理

  1. temperatureThen, the mixture was cooled to room temperature
  2. customthe organic layer was separated
  3. distillationThe resulting oil was purified by distillation

出典と根拠

ORDレコード
ord-01ef560744dd4ac19a42d01ff1cff912
出典データセット
uspto-grants-2003_09
特許番号
US06627763B2

反応ノート

読み込み中…