Benzene → N-(4-methoxyphenyl)-4-nitro-3-methylbenzene carboximidoyl chloride

HRID 1197868

反応式

HRID 1197868 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([NH:9][C:10](=O)[C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[C:13]([CH3:20])[CH:12]=2)=[CH:5][CH:4]=1.C1C=CC=CC=1.S(Cl)([Cl:30])=O>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([N:9]=[C:10]([Cl:30])[C:11]2[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[C:13]([CH3:20])[CH:12]=2)=[CH:5][CH:4]=1

参加物

4

反応物 3

HCID 241BenzeneHCID 24386Thionyl ChlorideHCID 790964N-(4-methoxyphenyl)-3-methyl-4-nitrobenzamide

生成物 1

HCID 13633435N-(4-methoxyphenyl)-4-nitro-3-methylbenzene carboximidoyl chloride

実験手順

14 g of N-(4-methoxyphenyl)-4-nitro-3-methyl benzamide in suspension in 70 ml of thionyl chloride were heated for 20 hours at reflux. The solvent was eliminated by entrainment with benzene, and after drying under reduced pressure at ambient temperature, 15 g of N-(4-methoxyphenyl)-4-nitro-3-methylbenzene carboximidoyl chloride melting towards 80° C. were obtained.

後処理

  1. temperatureat reflux
  2. customafter drying under reduced pressure at ambient temperature

出典と根拠

ORDレコード
ord-d6a32888520145e7b0f7ea42659d374a
出典データセット
uspto-grants-1994_01
特許番号
US05278180

関連ノート

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