N,N'-Dimethylethylenediamine → 1-(5,6-Diphenyl-pyrazin-2-yl)-propan-1-one
反応式
[C:1]1([C:7]2[N:8]=[CH:9][C:10]([C:19]([O:21]C)=O)=[N:11][C:12]=2[C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Al](CC)(CC)[CH2:24][CH3:25].CNCCNC>C1(C)C=CC=CC=1>[C:1]1([C:7]2[N:8]=[CH:9][C:10]([C:19](=[O:21])[CH2:24][CH3:25])=[N:11][C:12]=2[C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
5
実験手順
Following General Procedure O, methyl 5,6-diphenyl-pyrazine-2-carboxylate (Compound 93) (92 mg, 0.32 mmol), Et3Al (0.9 ml, 1M in hexane), DMEDA (38 mg, 0.35 mmol) in toluene was reacted to afford the title compound.
後処理
- customwas reacted
出典と根拠
- ORDレコード
- ord-c266ff78267141f78cd7efceb38cee8f
- 出典データセット
- uspto-grants-2010_06
- 特許番号
- US07728014B2
反応ノート
読み込み中…