4-Nitroaniline → C.I. Disperse Blue 11

HRID 1271505

反応式

HRID 1271505 の反応式
[N+:1]([C:4]1[CH:10]=[CH:9][C:7]([NH2:8])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH3:11][O:12][C:13]1[CH:19]=[C:18](OC)[CH:17]=[CH:16][C:14]=1[NH2:15].CN(C)[CH:24]=[O:25].C[N:28](C=O)C>>[NH2:28][C:18]1[C:17]([O:25][CH3:24])=[CH:16][C:14]([N:15]=[N:8][C:7]2[CH:9]=[CH:10][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=2)=[C:13]([O:12][CH3:11])[CH:19]=1

参加物

4

反応物 3

HCID 74754-NitroanilineHCID 176522,4-DimethoxyanilineHCID 17824068DMF dimethylformamide

生成物 1

HCID 80685C.I. Disperse Blue 11収率 70.6%

実験手順

A diazonium salt synthesized from 4-nitroaniline using the procedure of example 1 (1.4 g, 5.9 mmol) was added portionwise to a solution of 2,4-dimethoxyaniline (0.97 g, 6.3 mmol) in dimethylformamide DMF) (20 ml). The resulting red mixture was stirred for 1.5 h, filtered, and the resulting solid recrystallized from ethyl acetate (EtOAc)/Hexanes to give 1.3 g (70.6%) of Compound 5.

後処理

  1. filtrationfiltered
  2. customthe resulting solid recrystallized from ethyl acetate (EtOAc)/Hexanes

出典と根拠

ORDレコード
ord-b748b193acdc4aa9a494ab1595b9f84f
出典データセット
uspto-grants-2007_04
特許番号
US07205347B2

関連ノート

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