Hydrogen Bromide → 16-Bromohexadecanoic acid
反応式
O[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18].[BrH:20]>C(O)(=O)C>[Br:20][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18]参加物
4
実験手順
16-Bromohexadecanoic acid was prepared by refluxing for 48 hrs 5.0 gr (18.35 mmole) of 16-hydroxyhexadecanoic acid in 24 ml of 1:1 v/v mixture of HBr (48% aqueous solution) and glacial acetic acid. Upon cooling, crude product was solidified inside the reaction vessel. It was filtered out and washed with 3×100 ml of cold water. 6.1 gr (99% yield) of the desired product were obtained.
後処理
- custom16-Bromohexadecanoic acid was prepared
- temperatureUpon cooling
- filtrationIt was filtered out
- washwashed with 3×100 ml of cold water
出典と根拠
- ORDレコード
- ord-5c24e10a6f8444acbd4e7766507ebdd8
- 出典データセット
- uspto-grants-2008_06
- 特許番号
- US07384749B2
反応ノート
読み込み中…