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Azobisisobutyronitrile → hydroxystyrene (3-acryloxypropyl)trimethylsiloxy Silane

HRID 1355317
ノート
印刷プレビュー

反応式

HRID 1355317 の反応式
[C:1]([O:5][CH2:6][CH2:7][CH2:8][SiH2:9][O:10][Si:11]([CH3:14])([CH3:13])[CH3:12])(=[O:4])[CH:2]=[CH2:3].[OH:15][CH:16]=[CH:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[OH:15][CH:16]=[CH:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.[C:1]([O:5][CH2:6][CH2:7][CH2:8][SiH2:9][O:10][Si:11]([CH3:14])([CH3:12])[CH3:13])(=[O:4])[CH:2]=[CH2:3]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

5

反応物 3

HCID 6547AzobisisobutyronitrileHCID 138202HydroxystyreneHCID 131723942(3-Acryloxypropyl)trimethylsiloxy silane

生成物 1

HCID 131723941hydroxystyrene (3-acryloxypropyl)trimethylsiloxy Silane

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

反応条件

温度
65 °C

実験手順

15 g (3-acryloxypropyl)trimethylsiloxy silane, 40 g hydroxystyrene and 2.4 g AIBN were dissolved in 80 g THF and charged into a 3-neck flask. The system was then purged with N2 for 30 mins before the temperature was raised to 65° C. The reaction was carried out overnight under N2. On the second day, the solution was precipitated in 2000 mL water. The polymer was collected and dried in vacuum oven overnight at 40° C. The molecular weight was determined by GPC to be 9.1K and the molecular weight showed bimodal distribution.

後処理

  1. additioncharged into a 3-neck flask
  2. customThe system was then purged with N2 for 30 mins before the temperature
  3. customOn the second day, the solution was precipitated in 2000 mL water
  4. customThe polymer was collected
  5. customdried in vacuum oven overnight at 40° C

出典と根拠

ORDレコード
ord-e47fe2c4568c40619470eb68d7f38b34
出典データセット
uspto-grants-2003_07
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US06586156B2

反応ノート

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このページの内容参加物反応条件実験手順後処理出典と根拠反応ノート