8-Hydroxyquinoline → Aluminium tri(quinolin-8-olate)

HRID 1370984

反応式

HRID 1370984 の反応式
O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Al+3:22].S([O-])([O-])(=O)=O.S([O-])([O-])(=O)=O.[Al+3].[OH:34][C:35]1[CH:36]=[CH:37][CH:38]=[C:39]2[C:44]=1[N:43]=[CH:42][CH:41]=[CH:40]2.[OH-].[Na+]>O>[CH:37]1[CH:36]=[C:35]([O-:34])[C:44]2[N:43]=[CH:42][CH:41]=[CH:40][C:39]=2[CH:38]=1.[CH:37]1[CH:36]=[C:35]([O-:34])[C:44]2[N:43]=[CH:42][CH:41]=[CH:40][C:39]=2[CH:38]=1.[CH:37]1[CH:36]=[C:35]([O-:34])[C:44]2[N:43]=[CH:42][CH:41]=[CH:40][C:39]=2[CH:38]=1.[Al+3:22]

参加物

5

反応物 3

HCID 19238-HydroxyquinolineHCID 14798Sodium HydroxideHCID 23065692Aluminum sulfate hexadecahydrate

生成物 1

HCID 90594Aluminium tri(quinolin-8-olate)収率 197.6%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To 93 g of water were added 25 g of aluminum sulfate hexadecahydrate and 35 g of 99% pure 8-hydroxyquinoline and the mixture was neutralized by dropwise addition of 29 g of a 33% solution of sodium hydroxide with stirring and allowed to react. The solid formed was collected by filtration, washed with water and dried to give 36 g of Alq3.

後処理

  1. customto react
  2. customThe solid formed
  3. filtrationwas collected by filtration
  4. washwashed with water
  5. customdried

出典と根拠

ORDレコード
ord-b5b62ed6e0904eb8ba229573dda84fc8
出典データセット
uspto-grants-2003_06
特許番号
US06583583B1

関連ノート

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