8-Hydroxyquinoline → Aluminium tri(quinolin-8-olate)

HRID 1370985

反応式

HRID 1370985 の反応式
[NH4+].O.O.O.O.O.O.O.O.O.O.O.O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[Al+3:24].[OH:25][C:26]1[CH:27]=[CH:28][CH:29]=[C:30]2[C:35]=1[N:34]=[CH:33][CH:32]=[CH:31]2.[OH-].[Na+]>O>[CH:28]1[CH:27]=[C:26]([O-:25])[C:35]2[N:34]=[CH:33][CH:32]=[CH:31][C:30]=2[CH:29]=1.[CH:28]1[CH:27]=[C:26]([O-:25])[C:35]2[N:34]=[CH:33][CH:32]=[CH:31][C:30]=2[CH:29]=1.[CH:28]1[CH:27]=[C:26]([O-:25])[C:35]2[N:34]=[CH:33][CH:32]=[CH:31][C:30]=2[CH:29]=1.[Al+3:24]

参加物

5

反応物 3

HCID 19238-HydroxyquinolineHCID 14798Sodium HydroxideHCID 62668Ammonium alum

生成物 1

HCID 90594Aluminium tri(quinolin-8-olate)収率 91.3%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

As in Example 1, 22.7 g of ammonium alum and 21.8 g of 8-hydroxyquinoline were added to 150 g of water and the mixture was neutralized by dropwise addition of 6.5 g of a 33% solution of sodium hydroxide with stirring and allowed to react. The solid formed was washed with water and dried to give 21 g of Alq3. The raw material Alq3 thus prepared was refined in the metallic apparatus for refining by sublimation illustrated in FIG. 1 to give 11 g of refined Alq3.

後処理

  1. customto react
  2. customThe solid formed
  3. washwas washed with water
  4. customdried

出典と根拠

ORDレコード
ord-0391b7b0b2a542e9b2c41c57f2f5993e
出典データセット
uspto-grants-2003_06
特許番号
US06583583B1

関連ノート

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