Hydrazine hydrate (1:1) → HCID 178512741、化合物
反応式
[NH2:1][C:2]1[C:3]([C:7]#[N:8])=[N:4][O:5][N:6]=1.O.[NH2:10][NH2:11]>C(#N)C>[NH2:1][C:2]1[C:3]([C:7]([NH:10][NH2:11])=[NH:8])=[N:4][O:5][N:6]=1参加物
4
実験手順
To a solution of 4-amino-furazan-3-carbonitrile (0.50 g, 4.50 mmol) in acetonitrile (7.0 mL) was added hydrazine monohydrate (0.28 mL) dropwise. The solution was stirred at ambient temperature for 3 hours after which time a white solid precipitated. The solid was washed with acetonitrile and dried in vacuo to afford the title compound (0.60 g, 94%) as a white, fluffy solid. HPLC Method A Rt 0.18 min, m/z (ES+) (M+H)+ 143.
後処理
- customprecipitated
- washThe solid was washed with acetonitrile
- customdried in vacuo
出典と根拠
- ORDレコード
- ord-490b446c14f64b24b219f338e134535d
- 出典データセット
- uspto-grants-2007_01
- 特許番号
- US07157476B2
反応ノート
読み込み中…