Potassium Hydroxide → HCID 13281343、化合物
反応式
[Cl:1][C:2]1[C:13]2[CH2:12][CH2:11][CH2:10][C:9](=O)[C:8]3[CH:15]=[CH:16][CH:17]=[CH:18][C:7]=3[C:6]=2[CH:5]=[CH:4][CH:3]=1.O.NN.[OH-].[K+]>C(O)CO>[Cl:1][C:2]1[C:13]2[CH2:12][CH2:11][CH2:10][CH2:9][C:8]3[CH:15]=[CH:16][CH:17]=[CH:18][C:7]=3[C:6]=2[CH:5]=[CH:4][CH:3]=1参加物
5
実験手順
The reaction of 9-chloro-5,6,7,8-tetrahydrodibenzo[a,c]-cycloocten-5-one (3.0 g, 0.015 mole), 85% hydrazine hydrate (4.5 g, 0.076 mole), potassium hydroxide (3.0 g, 0.046 mole) and ethylene glycol (39 ml) produced an oil. The oil was purified by column chromatography on silica gel, eluted with toluene to yield 4-chloro-5,6,7,8-tetrahydrodibenzo[a,c]cyclooctene as an oil (3.3 grams).
後処理
- customproduced an oil
- customThe oil was purified by column chromatography on silica gel
- washeluted with toluene
出典と根拠
- ORDレコード
- ord-c62c125314254b93aa856cfdefdc59df
- 出典データセット
- uspto-grants-1984_02
- 特許番号
- US04433182
反応ノート
読み込み中…