Water → HCID 19842598、化合物

HRID 1390176ノート

反応式

HRID 1390176 の反応式
[Na].[I-].[C:3]([CH2:5][CH2:6][P+:7](CCC#N)([CH2:12][CH2:13][C:14]#[N:15])[CH2:8][CH2:9][O:10][CH3:11])#[N:4].O.C(Cl)(Cl)Cl>CO>[C:3]([CH2:5][CH2:6][P:7]([CH2:12][CH2:13][C:14]#[N:15])[CH2:8][CH2:9][O:10][CH3:11])#[N:4]

参加物

6

反応物 4

HCID 962WaterHCID 6212ChloroformHCID 5360545SodiumHCID 20520070HCID 20520070、化合物

生成物 1

HCID 19842598HCID 19842598、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

1.55 g of sodium are dissolved in 100 ml of absolute methanol under an atmosphere of argon and then 26 g (0.0685 mole) of tris-(β-cyanoethyl)-2-methoxyethyl-phosphonium iodide are added to this solution. The solution is refluxed for 4 hours. After the mixture has been poured into water, extraction is performed with three 40 ml portions of chloroform. The chloroform solution is dried over magnesium sulphate, the solvent is evaporated and the oily residue distilled in a high vacuum.

後処理

  1. temperatureThe solution is refluxed for 4 hours
  2. dry with materialThe chloroform solution is dried over magnesium sulphate
  3. customthe solvent is evaporated
  4. distillationthe oily residue distilled in a high vacuum

出典と根拠

ORDレコード
ord-3b12450557754a49a931e5938d1173c2
出典データセット
uspto-grants-1979_02
特許番号
US04138256

反応ノート

読み込み中…