2-(2,6-Dinitrophenylamino)ethanol → HCID 23362032、化合物

HRID 1398934ノート

反応式

HRID 1398934 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-])=O)[C:5]=1[NH:13][CH2:14][CH2:15][OH:16])([O-])=O>[Pd].O1CCCC1>[NH2:1][C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([NH2:10])[C:5]=1[NH:13][CH2:14][CH2:15][OH:16]

参加物

4

反応物 1

HCID 233620182-(2,6-Dinitrophenylamino)ethanol

生成物 1

HCID 23362032HCID 23362032、化合物収率 89%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 8028Tetrahydrofuran溶媒

実験手順

Under hydrogen gas atmosphere, a mixture of 2-[(2,6-dinitrophenyl)amino]ethanol (5.54 g, 24.4 mmol) and 10% palladium on carbon (50% wet, 1.1 g) in tetrahydrofuran (240 mL) was stirred at room temperature for 2 h. The reaction mixture was filtered and concentrated in vacuo to give the title compound as a brown oil (3.63 g, 21.7 mmol, 89%).

後処理

  1. filtrationThe reaction mixture was filtered
  2. concentrationconcentrated in vacuo

出典と根拠

ORDレコード
ord-b048dc9fd0c946ee98d0beb40350427f
出典データセット
uspto-grants-2014_12
特許番号
US08901141B2

反応ノート

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