Methyl iodide → HCID 178439609、化合物

HRID 1399403ノート

反応式

HRID 1399403 の反応式
[CH2:1]([C:4]1[N:5]=[N:6][N:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[CH:8]=1)[CH2:2][CH3:3].[I:14][CH3:15]>C(#N)C>[I-:14].[CH3:15][N+:5]1[C:4]([CH2:1][CH2:2][CH3:3])=[CH:8][N:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[N:6]=1

参加物

4

反応物 2

HCID 6328Methyl iodideHCID 131732124HCID 131732124、化合物

生成物 1

HCID 178439609HCID 178439609、化合物

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazole and excess iodomethane were added to a vial and heated for about 19 and 5 mL ACN was added. The reaction was heated for another 2 hours. The precipitate was filtered, rinsed with ether and dried in vacuo overnight. The following 3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide structure was confirmed:

後処理

  1. additionwas added
  2. temperatureThe reaction was heated for another 2 hours
  3. filtrationThe precipitate was filtered
  4. washrinsed with ether
  5. customdried in vacuo overnight

出典と根拠

ORDレコード
ord-cc5166db45ee4999b0aeb2f941762d4d
出典データセット
uspto-grants-2014_12
特許番号
US08906135B1

反応ノート

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