Hexafluoropropylene → Cyclopentane, (1,1,2,3,3,3-hexafluoropropyl)-

反応式

[CH2:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][C:7]([F:14])([F:13])[C:8]([F:12])=[C:9]([F:11])[F:10]>>[F:10][C:9]([CH:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1)([F:11])[CH:8]([F:12])[C:7]([F:14])([F:13])[F:6]

参加物

反応物 2

HCID 8302Hexafluoropropylene

HCID 9253Cyclopentane

生成物 1

HCID 10632697Cyclopentane, (1,1,2,3,3,3-hexafluoropropyl)-収率 71%

実験手順

Cyclopentane (65 mmole) and hexafluoropropene (22 mmole) heated at 290° for 2 days gave a 71% yield (based on hexafluoropropene consumed) of analytically and spectroscopically pure 1,1,2,3,3,3-hexafluoropropylcyclopentane: ##STR15## identical with material prepared by an alternative route.

後処理

customgave
customa 71% yield (based on hexafluoropropene consumed) of analytically and spectroscopically pure 1,1,2,3,3,3-hexafluoropropylcyclopentane
custom##STR15## identical with material prepared by an alternative route

出典と根拠

ORDレコード: ord-7ffad86ee0864642a0e27b540afdb498
出典データセット: uspto-grants-1977_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04002810

反応ノート

読み込み中…

参加物