Chloride → Acrylamide

HRID 1418786

反応式

HRID 1418786 の反応式
[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[Cl-:6].[C:7]([O:11][CH2:12][CH3:13])(=[O:10])[CH:8]=[CH2:9].C(N(CC(O)=O)CC(O)=O)CN(CC(O)=O)CC(O)=O.Cl.Cl.N(C(C1NCCN=1)(C)C)=NC(C1NCCN=1)(C)C>O>[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[CH3:7][Cl:6].[C:7]([O:11][CH2:12][CH3:13])(=[O:10])[CH:8]=[CH2:9]

参加物

8

反応物 5

HCID 312ChlorideHCID 6049Ethylenediaminetetraacetic AcidHCID 6579AcrylamideHCID 8821Ethyl AcrylateHCID 99491012,2'-Azobis[2-(2-imidazolin-2-yl)propane] dihydrochloride

生成物 2

HCID 6579AcrylamideHCID 23497919MeCl EA

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A 10% solution of poly(AMD/DMAEA.MeCl/EA) was prepared as follows: 13.87 parts of 53.58% aqueous acrylamide (AMD), 25.31 parts of a 80% aqueous solution of ethacryloxyethyltrimethylammonium chloride (DMAEA.MeCl), 2.33 parts of ethyl acrylate (EA), 0.3 part EDTA, 258.16 parts of deionized water and 0.030 parts of VA-044 were added to a suitable glass vessel. The solution was sparged with nitrogen gas and stirred for about one hour at ambient temperature. The nitrogen sparge was changed to a nitrogen purge, and polymerization was initiated thermally by raising the temperature of the solution to 44° C. Stirring and heating were continued for about 21 hours to give a clear, viscous solution of poly(AMD/DMAEA.MeCl/EA) having a standard viscosity of about 2.0 centipoise.

後処理

  1. customThe solution was sparged with nitrogen gas
  2. customThe nitrogen sparge
  3. custompurge
  4. custompolymerization
  5. temperatureby raising the temperature of the solution to 44° C
  6. stirringStirring
  7. temperatureheating
  8. waitwere continued for about 21 hours

出典と根拠

ORDレコード
ord-72ec4339c2cc4562806994de9068f966
出典データセット
uspto-grants-1999_03
特許番号
US05885032

関連ノート

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