1-Bromo-2-nitrobenzene → HCID 23087148、化合物

HRID 1433864

反応式

HRID 1433864 の反応式
Br[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9].C([Sn](CCCC)(CCCC)C1C=CC=CC=1[N+]([O-])=O)CCC.FC(F)(F)S(O[C:39]1[CH2:48][CH2:47][C:46]2[C:41](=[CH:42][CH:43]=[C:44]([O:49][CH3:50])[CH:45]=2)[CH:40]=1)(=O)=O>>[CH3:50][O:49][C:44]1[CH:45]=[C:46]2[C:41]([CH:40]=[C:39]([C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=3[N+:8]([O-:10])=[O:9])[CH2:48][CH2:47]2)=[CH:42][CH:43]=1

参加物

4

反応物 3

HCID 113411-Bromo-2-nitrobenzeneHCID 11338886Stannane, tributyl(2-nitrophenyl)-HCID 153302566-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate

生成物 1

HCID 23087148HCID 23087148、化合物

実験手順

Synthesized from 1-bromo-2-nitrobenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitrophenyl)tin (7.3 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (1.5 g).

後処理

  1. customwere used according to an analogous synthetic method to Preparation Example 77

出典と根拠

ORDレコード
ord-b32ce141dc53404ea6e4e18e82ce31b5
出典データセット
uspto-grants-2009_11
特許番号
US07612114B2

関連ノート

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