Ethanesulfonylchloride, 2-chloro- → Dimethyl 2-vinylsulfonyloxyethylphosphonate

HRID 1439316ノート

反応式

HRID 1439316 の反応式
[OH:1][CH2:2][CH2:3][P:4](=[O:9])([O:7][CH3:8])[O:5][CH3:6].Cl[CH2:11][CH2:12][S:13](Cl)(=[O:15])=[O:14]>N1C=CC=CC=1>[CH:12]([S:13]([O:1][CH2:2][CH2:3][P:4](=[O:9])([O:7][CH3:8])[O:5][CH3:6])(=[O:15])=[O:14])=[CH2:11]

参加物

4

反応物 2

HCID 15385Ethanesulfonylchloride, 2-chloro-HCID 2733833Dimethyl (2-hydroxyethyl)phosphonate

生成物 1

HCID 21396800Dimethyl 2-vinylsulfonyloxyethylphosphonate

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

Dimethyl 2-vinylsulfonyloxyethylphosphonate was prepared in the same way as in Example 1 from 3.8 g of dimethyl 2-hydroxyethylphosphonate, 1.9 g of pyridine and 4.0 g of 2-chloroethylsulfonyl chloride. The yield was 20 mol%. The NMR spectrum (CDCl3) of this product was as follows:

出典と根拠

ORDレコード
ord-62596728e2b541f7b9403d1969fbee66
出典データセット
uspto-grants-1977_11
特許番号
US04059432

反応ノート

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