Pyridine → HCID 15067105、化合物

HRID 1460373ノート

反応式

HRID 1460373 の反応式
[CH2:1]([O:3][CH2:4][CH2:5][OH:6])[CH3:2].N1C=CC=CC=1.[S:13](Cl)([CH3:16])(=[O:15])=[O:14]>O1CCCC1>[CH3:16][S:13]([O:6][CH2:5][CH2:4][O:3][CH2:1][CH3:2])(=[O:15])=[O:14]

参加物

5

反応物 3

HCID 1049PyridineHCID 8076Glycol monoethyl etherHCID 31297Methanesulfonyl chloride

生成物 1

HCID 15067105HCID 15067105、化合物

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

To 30g of 2-ethoxyethanol in 300ml of tetrahydrofuran 27.4ml of pyridine were added and 26.4ml of mesyl chloride added dropwise at room temperature over 15 minutes. The mixture was refluxed overnight, the solid that formed filtered off and the solvent evaporated off from the residue. The residue was distilled under 20m Hg to give 2-ethoxyethyl methanesulphonate.

後処理

  1. temperatureThe mixture was refluxed overnight
  2. customthe solid that formed
  3. filtrationfiltered off
  4. customthe solvent evaporated off from the residue
  5. distillationThe residue was distilled under 20m Hg

出典と根拠

ORDレコード
ord-f8da1dc8ee6d42478c217b4800fba461
出典データセット
uspto-grants-1991_12
特許番号
US05071468

反応ノート

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