Dimethylformamide → N,N,N-Trimethyl-N-[3-(tris-trimethylsiloxy-silyl)-propyl]ammonium iodide

HRID 1478941ノート

反応式

HRID 1478941 の反応式
NC[CH2:3][CH2:4][Si:5]([O:16][Si:17]([CH3:20])([CH3:19])[CH3:18])([O:11][Si:12]([CH3:15])([CH3:14])[CH3:13])[O:6][Si:7]([CH3:10])([CH3:9])[CH3:8].[CH3:21][I:22].C(=O)([O-])[O-].[Na+].[Na+].[CH3:29][N:30]([CH3:33])[CH:31]=O>>[I-:22].[CH3:29][N+:30]([CH3:33])([CH3:21])[CH2:31][CH2:3][CH2:4][Si:5]([O:11][Si:12]([CH3:13])([CH3:15])[CH3:14])([O:16][Si:17]([CH3:20])([CH3:19])[CH3:18])[O:6][Si:7]([CH3:8])([CH3:9])[CH3:10]

参加物

5

反応物 4

HCID 6228DimethylformamideHCID 6328Methyl iodideHCID 10340Sodium CarbonateHCID 2756547(3-Aminopropyl)tris(trimethylsiloxy)silane

生成物 1

HCID 86670508N,N,N-Trimethyl-N-[3-(tris-trimethylsiloxy-silyl)-propyl]ammonium iodide

実験手順

0.8 g of 3-aminopropyltris(trimethylsiloxy)silane, 1.8 g of methyl iodide and 1.35 g of sodium carbonate are added to 50 ml of dimethylformamide. The reaction mixture is stirred for 3 hours at room temperature. The solvent is evaporated and the residue taken in methylene chloride and water. The organic phase is then washed with water, dried and evaporated whereby compound (35) is obtained; 1H-NMR (ppm, CDCl3): 3.45-3.32 11H m, 1.68-1.58 2H m, 0.39 2H t, 0.00 27H s.

後処理

  1. customThe solvent is evaporated
  2. washThe organic phase is then washed with water
  3. customdried
  4. customevaporated whereby compound (35)
  5. customis obtained

出典と根拠

ORDレコード
ord-c15b8169feb64484b8e0892570a0f430
出典データセット
uspto-grants-2016_08
特許番号
US09403987B2

反応ノート

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