Tetrahydrofuran → Benzoyloxymethyl chloroformate
反応式
[C:1]([O:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]CCCCCCCCC(O)=O)(=[O:17])CCCCCCCCCCCCCCC.C(Cl)(=O)[C:38]([Cl:40])=[O:39].[O:43]1CCCC1>>[Cl:40][C:38]([O:17][CH2:1][O:18][C:19](=[O:43])[C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)=[O:39]参加物
4
実験手順
16-Hexadecanoyloxyhexadecanoic acid (7.73 g, 15.13 mmol) prepared as in (ah) above was dissolved in tetrahydrofuran (140 ml) and oxalyl chloride (4.80 g, 37.83 mmol) was added dropwise. The mixture was stirred at room temperature for 3 days and then the solvent and unreacted oxalyl chloride were evaporated under reduced pressure to give 8.0 g (100%) of the title compound.
後処理
- customthe solvent and unreacted oxalyl chloride were evaporated under reduced pressure
出典と根拠
- ORDレコード
- ord-23aacdf1cc0a48efbb8e8ac50c09a943
- 出典データセット
- uspto-grants-1997_10
- 特許番号
- US05674468
反応ノート
読み込み中…