5-Methoxy-2-methylbenzoxazole → 5-Methoxy-2-methyl-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzoxazole

HRID 1490443

反応式

HRID 1490443 の反応式
COc1ccc2oc(C)nc2c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>COc1cc(B2OC(C)(C)C(C)(C)O2)c2oc(C)nc2c1

参加物

6

反応物 1

HCID 797595-Methoxy-2-methylbenzoxazole

生成物 1

HCID 1018796725-Methoxy-2-methyl-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzoxazole収率 61%

試薬・触媒・溶媒 4

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthroline試薬HCID 2733548Bis(pinacolato)diborane試薬HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium触媒HCID 8028Tetrahydrofuran溶媒

反応条件

温度
25 °C

出典と根拠

ORDレコード
ord-f50e2c51477b40e7a3262680682260d9
出典データセット
Borylation dataset from Roche

関連ノート

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