反応式
COC(=O)c1cccc(SC)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.Cc1ccnc(-c2cc(C)ccn2)c1.[Ir].[Ir]>COC(=O)c1cc(SC)cc(B2OC(C)(C)C(C)(C)O2)c1参加物
6
反応条件
- 温度
- 55 °C
実験手順
dtbpy: A mixture of ortho- and meta-borylated products (128 mg, 83% yield, ortho/meta + para = <0.01); meta-Isomer 5pwas obtained by further purification by GPC (116 mg, 75% yield), white solid (mp. 115-117 oC)
出典と根拠
- ORDレコード
- ord-76f3f83feb2744bb84a39a38dd5be253
- 出典データセット
- Borylation dataset from Roche
関連ノート
読み込み中…